A System of Logic: Ratiocinative and Inductive, 7th Edition, Vol. I

by John Stuart Mill

But the rigorous conditions of the Method of Difference are not yet satisfied; for we cannot be sure that these unpoisonous bodies agree with the poisonous substances in every property, except the particular one, of entering into a difficultly decomposable compound with the animal tissues. To render the method strictly applicable, we need an instance, not of a different substance, but of one of the very same substances, in circumstances which would prevent it from forming, with the tissues, the sort of compound in question; and then, if death does not follow, our case is made out. Now such instances are afforded by the antidotes to these poisons. For example, in case of poisoning by arsenious acid, if hydrated peroxide of iron is administered, the destructive agency is instantly checked. Now this peroxide is known to combine with the acid, and form a compound, which, being insoluble, cannot act at all on animal tissues. So, again, sugar is a well-known antidote to poisoning by salts of copper; and sugar reduces those salts either into metallic copper, or into the red suboxide, neither of which enters into combination with animal matter. The disease called painter's colic, so common in manufactories of white lead, is unknown where the workmen are accustomed to take, as a preservative, sulphuric acid lemonade (a solution of sugar rendered acid by sulphuric acid). Now diluted sulphuric acid has the property of decomposing all compounds of lead with organic matter, or of preventing them from being formed.

There is another class of instances, of the nature required by the Method of Difference, which seem at first sight to conflict with the theory. Soluble salts of silver, such for instance as the nitrate, have the same stiffening antiseptic effect on decomposing animal substances as corrosive sublimate and the most deadly metallic poisons; and when applied to the external parts of the body, the nitrate is a powerful caustic; depriving those parts of all active vitality, and causing them to be thrown off by the neighbouring living structures, in the form of an eschar. The nitrate and the other salts of silver ought, then, it would seem, if the theory be correct, to be poisonous; yet they may be administered internally with perfect impunity. From this apparent exception arises the strongest confirmation which the theory has yet received. Nitrate of silver, in spite of its chemical properties, does not poison when introduced into the stomach; but in the stomach, as in all animal liquids, there is common salt; and in the stomach there is also free muriatic acid. These substances operate as natural antidotes, combining with the nitrate, and if its quantity is not too great, immediately converting it into chloride of silver; a substance very slightly soluble, and therefore incapable of combining with the tissues, although to the extent of its solubility it has a medicinal influence, though an entirely different class of organic actions.

The preceding instances have afforded an induction of a high order of conclusiveness, illustrative of the two simplest of our four methods; though not rising to the maximum of certainty which the Method of Difference, in its most perfect exemplification, is capable of affording. For (let us not forget) the positive instance and the negative one which the rigour of that method requires, ought to differ only in the presence or absence of one single circumstance. Now, in the preceding argument, they differ in the presence or absence not of a single circumstance, but of a single substance: and as every substance has innumerable properties, there is no knowing what number of real differences are involved in what is nominally and apparently only one difference. It is conceivable that the antidote, the peroxide of iron for example, may counteract the poison through some other of its properties than that of forming an insoluble compound with it; and if so, the theory would fall to the ground, so far as it is supported by that instance. This source of uncertainty, which is a serious hindrance to all extensive generalizations in chemistry, is however reduced in the present case to almost the lowest degree possible, when we find that not only one substance, but many substances, possess the capacity of acting as antidotes to metallic poisons, and that all these agree in the property of forming insoluble compounds with the poisons, while they cannot be ascertained to agree in any other property whatsoever. We have thus, in favour of the theory, all the evidence which can be obtained by what we termed the Indirect Method of Difference, or the Joint Method of Agreement and Difference; the evidence of which, though it never can amount to that of the Method of Difference properly so called, may approach indefinitely near to it.

[§ 2.] Let the object be[34] to ascertain the law of what is termed induced electricity; to find under what conditions any electrified body, whether positively or negatively electrified, gives rise to a contrary electric state in some other body adjacent to it.

The most familiar exemplification of the phenomenon to be investigated is the following. Around the prime conductors of an electrical machine, the atmosphere to some distance, or any conducting surface suspended in that atmosphere, is found to be in an electric condition opposite to that of the prime conductor itself. Near and around the positive prime conductor there is negative electricity, and near and around the negative prime conductor there is positive electricity. When pith balls are brought near to either of the conductors, they become electrified with the opposite electricity to it; either receiving a share from the already electrified atmosphere by conduction, or acted upon by the direct inductive influence of the conductor itself: they are then attracted by the conductor to which they are in opposition; or, if withdrawn in their electrified state, they will be attracted by any other oppositely charged body. In like manner the hand, if brought near enough to the conductor, receives or gives an electric discharge; now we have no evidence that a charged conductor can be suddenly discharged unless by the approach of a body oppositely electrified. In the case, therefore, of the electric machine, it appears that the accumulation of electricity in an insulated conductor is always accompanied by the excitement of the contrary electricity in the surrounding atmosphere, and in every conductor placed near the former conductor. It does not seem possible, in this case, to produce one electricity by itself.

Let us now examine all the other instances which we can obtain, resembling this instance in the given consequent, namely, the evolution of an opposite electricity in the neighbourhood of an electrified body. As one remarkable instance we have the Leyden jar; and after the splendid experiments of Faraday in complete and final establishment of the substantial identity of magnetism and electricity, we may cite the magnet, both the natural and the electro-magnet, in neither of which it is possible to produce one kind of electricity by itself, or to charge one pole without charging an opposite pole with the contrary electricity at the same time. We cannot have a magnet with one pole: if we break a natural loadstone into a thousand pieces, each piece will have its two oppositely electrified poles complete within itself. In the voltaic circuit, again, we cannot have one current without its opposite. In the ordinary electric machine, the glass cylinder or plate, and the rubber, acquire opposite electricities.

From all these instances, treated by the Method of Agreement, a general law appears to result. The instances embrace all the known modes in which a body can become charged with electricity; and in all of them there is found, as a concomitant or consequent, the excitement of the opposite electric state in some other body or bodies. It seems to follow that the two facts are invariably connected, and that the excitement of electricity in any body has for one of its necessary conditions the possibility of a simultaneous excitement of the opposite electricity in some neighbouring body.

As the two contrary electricities can only be produced together, so they can only cease together. This may be shown by an application of the Method of Difference to the example of the Leyden jar. It needs scarcely be here remarked that in the Leyden jar, electricity can be accumulated and retained in considerable quantity, by the contrivance of having two conducting surfaces of equal extent, and parallel to each other through the whole of that extent, with a non-conducting substance such as glass between them. When one side of the jar is charged positively, the other is charged negatively, and it was by virtue of this fact that the Leyden jar served just now as an instance in our employment of the Method of Agreement. Now it is impossible to discharge one of the coatings unless the other can be discharged at the same time. A conductor held to the positive side cannot convey away any electricity unless an equal quantity be allowed to pass from the negative side: if one coating be perfectly insulated, the charge is safe. The dissipation of one must proceed pari passu with that of the other.

The law thus strongly indicated admits of corroboration by the Method of Concomitant Variations. The Leyden jar is capable of receiving a much higher charge than can ordinarily be given to the conductor of an electrical machine. Now in the case of the Leyden jar, the metallic surface which receives the induced electricity is a conductor exactly similar to that which receives the primary charge, and is therefore as susceptible of receiving and retaining the one electricity, as the opposite surface of receiving and retaining the other; but in the machine, the neighbouring body which is to be oppositely electrified is the surrounding atmosphere, or any body casually brought near to the conductor; and as these are generally much inferior in their capacity of becoming electrified, to the conductor itself, their limited power imposes a corresponding limit to the capacity of the conductor for being charged. As the capacity of the neighbouring body for supporting the opposition increases, a higher charge becomes possible: and to this appears to be owing the great superiority of the Leyden jar.