To preserve thought continuous throughout this discourse, to prevent either lack of knowledge or failure of memory from producing any rent in our picture, I here propose to run rapidly over a bit of ground which is probably familiar to most of you, but which I am anxious to make familiar to you all. The waves generated in the ether by the swinging atoms of luminous bodies are of different lengths and amplitudes. The amplitude is the width of swing of the individual particles of the wave. In water-waves it is the height of the crest above the trough, while the length of the wave is the distance between two consecutive crests. The aggregate of waves emitted by the sun may be broadly divided into two classes: the one class competent, the other incompetent, to excite vision. But the light-producing waves differ markedly among themselves in size, form, and force. The length of the largest of these waves is about twice that of the smallest, but the amplitude of the largest is probably a hundred times that of the smallest. Now the force or energy of the wave, which, expressed with reference to sensation, means the intensity of the light, is proportional to the square of the amplitude. Hence the amplitude being one-hundredfold, the energy of the largest light-giving waves would be ten-thousandfold that of the smallest. This is not improbable. I use these figures not with a view to numerical accuracy, but to give you definite ideas of the differences that probably exist among the light-giving waves. And if we take the whole range of solar radiation into account—its non-visual as well as its visual waves—I think it probable that the force or energy of the largest wave is a million times that of the smallest.
Turned into their equivalents of sensation, the different light-waves produce different colours. Red, for example, is produced by the largest waves, violet by the smallest, while green is produced by a wave of intermediate length and amplitude. On entering from air into more highly refracting substances, such as glass or water, or the sulphide of carbon, all the waves are retarded, but the smallest ones most. This furnishes a means of separating the different classes of waves from each other; in other words, of analysing the light. Sent through a refracting prism, the waves of the sun are turned aside in different degrees from their direct course, the red least, the violet most. They are virtually pulled asunder, and they paint upon a white screen placed to receive them ‘the solar spectrum.’ Strictly speaking, the spectrum embraces an infinity of colours, but the limits of language and of our powers of distinction cause it to be divided into seven segments: red, orange, yellow, green, blue, indigo, violet. These are the seven primary or prismatic colours. Separately, or mixed in various proportions, the solar waves yield all the colours observed in nature and employed in art. Collectively, they give us the impression of whiteness. Pure unsifted solar light is white; and if all the wave-constituents of such light be reduced in the same proportion, the light, though diminished in intensity, will still be white. The whiteness of Alpine snow with the sun shining upon it, is barely tolerable to the eye. The same snow under an overcast firmament is still white. Such a firmament enfeebles the light by reflection, and when we lift ourselves above a cloud-field—to an Alpine summit, for instance, or to the top of Snowdon—and see, in the proper direction, the sun shining on the clouds, they appear dazzlingly white. Ordinary clouds, in fact, divide the solar light impinging on them into two parts—a reflected part and a transmitted part, in each of which the proportions of wave-motion which produce the impression of whiteness are sensibly preserved.
It will be understood that the conditions of whiteness would fail if all the waves were diminished equally, or by the same absolute quantity. They must be reduced proportionately, instead of equally. If by the act of reflexion the waves of red light are split into exact halves, then, to preserve the light white, the waves of yellow, orange, green, and blue must also be split into exact halves. In short, the reduction must take place, not by absolutely equal quantities, but by equal fractional parts. In white light the preponderance as regards energy of the larger over the smaller waves must always be immense. Were the case otherwise, the physiological correlative, blue, of the smaller waves would have the upper hand in our sensations.
My wish to render our mental images complete, causes me to dwell briefly upon these known points, and the same wish will cause me to linger a little longer among others. But here I am disturbed by my reflections. When I consider the effect of dinner upon the nervous system, and the relation of that system to the intellectual powers I am now invoking—when I remember that the universal experience of mankind has fixed upon certain definite elements of perfection in an after-dinner speech, and when I think how conspicuous by their absence these elements are on the present occasion, the thought is not comforting to a man who wishes to stand well with his fellow-creatures in general, and with the members of the British Association in particular. My condition might well resemble that of the ether, which is scientifically defined as an assemblage of vibrations. And the worst of it is that unless you reverse the general verdict regarding the effect of dinner, and prove in your own persons that a uniform experience need not continue uniform—which will be a great point gained for some people—these tremors of mine are likely to become more and more painful. But I call to mind the comforting words of an inspired though uncanonical writer, who admonishes us in the Apocrypha that fear is a bad counsellor. Let me then cast him out, and let me trustfully assume that you will one and all postpone that balmy sleep, of which dinner might under the circumstances be regarded as the indissoluble antecedent, and that you will manfully and womanfully prolong your investigations of the ether and its waves into regions which have been hitherto crossed by the pioneers of science alone.
Not only are the waves of ether reflected by clouds, by solids, and by liquids, but when they pass from light air to dense, or from dense air to light, a portion of the wave-motion is always reflected. Now our atmosphere changes continually in density from top to bottom. It will help our conceptions if we regard it as made up of a series of thin concentric layers, or shells of air, each shell being of the same density throughout, and a small and sudden change of density occurring in passing from shell to shell. Light would be reflected at the limiting surfaces of all these shells, and their action would be practically the same as that of the real atmosphere. And now I would ask your imagination to picture this act of reflection. What must become of the reflected light? The atmospheric layers turn their convex surfaces towards the sun, they are so many convex mirrors of feeble power, and you will immediately perceive that the light regularly reflected from these surfaces cannot reach the earth at all, but is dispersed in space.
But though the sun’s light is not reflected in this fashion from the aërial layers to the earth, there is indubitable evidence to show that the light of our firmament is reflected light. Proofs of the most cogent description could be here adduced; but we need only consider that we receive light at the same time from all parts of the hemisphere of heaven. The light of the firmament comes to us across the direction of the solar rays, and even against the direction of the solar rays; and this lateral and opposing rush of wave-motion can only be due to the rebound of the waves from the air itself, or from something suspended in the air. It is also evident that, unlike the action of clouds, the solar light is not reflected by the sky in the proportions which produce white. The sky is blue, which indicates a deficiency on the part of the larger waves. In accounting for the colour of the sky, the first question suggested by analogy would undoubtedly be, is not the air blue? The blueness of the air has in fact been given as a solution of the blueness of the sky. But reason basing itself on observation, asks in reply, How, if the air be blue, can the light of sunrise and sunset, which travels through vast distances of air, be yellow, orange, or even red? The passage of the white solar light through a blue medium could by no possibility redden the light. The hypothesis of a blue air is therefore untenable. In fact the agent, whatever it is, which sends us the light of the sky, exercises in so doing a dichroitic action. The light reflected is blue, the light transmitted is orange or red. A marked distinction is thus exhibited between the matter of the sky and that of an ordinary cloud, which latter exercises no such dichroitic action.
By the force of imagination and reason combined we may penetrate this mystery also. The cloud takes no note of size on the part of the waves of ether, but reflects them all alike. It exercises no selective action. Now the cause of this may be that the cloud particles are so large in comparison with the size of the waves of ether as to reflect them all indifferently. A broad cliff reflects an Atlantic roller as easily as a ripple produced by a sea-bird’s wing; and in the presence of large reflecting surfaces, the existing differences of magnitude among the waves of ether may disappear. But supposing the reflecting particles, instead of being very large, to be very small, in comparison with the size of the waves. In this case, instead of the whole wave being fronted and in great part thrown back, a small portion only is shivered off. The great mass of the wave passes over such a particle without reflection. Scatter then a handful of such minute foreign particles in our atmosphere, and set imagination to watch their action upon the solar waves. Waves of all sizes impinge upon the particles, and you see at every collision a portion of the impinging wave struck off by reflection. All the waves of the spectrum, from the extreme red to the extreme violet, are thus acted upon. But in what proportions will the waves be scattered? A clear picture will enable us to anticipate the experimental answer. Remembering that the red waves are to the blue much in the relation of billows to ripples, let us consider whether those extremely small particles are competent to scatter all the waves in the same proportion. If they be not—and a little reflection will make it clear to you that they are not—the production of colour must be an incident of the scattering. Largeness is a thing of relation; and the smaller the wave, the greater is the relative size of any particle on which the wave impinges, and the greater also the ratio of the reflected portion to the total wave. A pebble placed in the way of the ring-ripples produced by our heavy rain-drops on a tranquil pond will throw back a large fraction of the ripple incident upon it, while the fractional part of a larger wave thrown back by the same pebble might be infinitesimal. Now we have already made it clear to our minds that to preserve the solar light white, its constituent proportions must not be altered; but in the act of division performed by these very small particles we see that the proportions are altered; an undue fraction of the smaller waves is scattered by the particles, and, as a consequence, in the scattered light, blue will be the predominant colour. The other colours of the spectrum must, to some extent, be associated with the blue. They are not absent but deficient. We ought, in fact, to have them all, but in diminishing proportions, from the violet to the red.
We have here presented a case to the imagination, and, assuming the undulatory theory to be a reality, we have, I think, fairly reasoned our way to the conclusion, that were particles, small in comparison to the size of the ether waves, sown in our atmosphere, the light scattered by those particles would be exactly such as we observe in our azure skies. When this light is analysed, all the colours of the spectrum are found; but they are found in the proportions indicated by our conclusion.
Let us now turn our attention to the light which passes unscattered among the particles. How must it be finally affected? By its successive collisions with the particles the white light is more and more robbed of its shorter waves; it therefore loses more and more of its due proportion of blue. The result may be anticipated. The transmitted light, where short distances are involved, will appear yellowish. But as the sun sinks towards the horizon the atmospheric distances increase, and consequently the number of the scattering particles. They abstract in succession the violet, the indigo, the blue, and even disturb the proportions of green. The transmitted light under such circumstances must pass from yellow through orange to red. This also is exactly what we find in nature. Thus, while the reflected light gives us at noon the deep azure of the Alpine skies, the transmitted light gives us at sunset the warm crimson of the Alpine snows. The phenomena certainly occur as if our atmosphere were a medium rendered slightly turbid by the mechanical suspension of exceedingly small foreign particles.
Here, as before, we encounter our sceptical ‘as if.’ It is one of the parasites of science, ever at hand, and ready to plant itself and sprout, if it can, on the weak points of our philosophy. But a strong constitution defies the parasite, and in our case, as we question the phenomena, probability grows like growing health, until in the end the malady of doubt is completely extirpated. The first question that naturally arises is—Can small particles be really proved to act in the manner indicated? No doubt of it. Each one of you can submit the question to an experimental test. Water will not dissolve resin, but spirit will; and when spirit which holds resin in solution is dropped into water, the resin immediately separates in solid particles, which render the water milky. The coarseness of this precipitate depends on the quantity of the dissolved resin. You can cause it to separate in thick clots or in exceedingly fine particles. Professor Brücke has given us the proportions which produce particles particularly suited to our present purpose. One gramme of clean mastic is dissolved in eighty-seven grammes of absolute alcohol, and the transparent solution is allowed to drop into a beaker containing clear water kept briskly stirred. An exceedingly fine precipitate is thus formed, which declares its presence by its action upon light. Placing a dark surface behind the beaker, and permitting the light to fall into it from the top or front, the medium is seen to be distinctly blue. It is not perhaps so perfect a blue as I have seen on exceptional days, this year, among the Alps, but it is a very fair sky-blue. A trace of soap in water gives a tint of blue. London, and I fear Liverpool milk, makes an approximation to the same colour through the operation of the same cause; and Helmholtz has irreverently disclosed the fact that a blue eye is simply a turbid medium.