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[5. Formation of Invisible Foci.]
This extraordinary deportment of the elementary gases naturally directed attention to elementary bodies in other states of aggregation. Some of Melloni's results now attained a new significance. This celebrated experimenter had found crystals of sulphur to be highly pervious to radiant heat; he had also proved that lamp-black, and black glass, (which owes its blackness to the element carbon) were to a considerable extent transparent to calorific rays of low refrangibility. These facts, harmonising so strikingly with the deportment of the simple gases, suggested further enquiry. Sulphur dissolved in bisulphide of carbon was found almost perfectly diathermic. The dense and deeply-coloured element bromine was examined, and found competent to cut off the light of our most brilliant flames, while it transmitted the invisible calorific rays with extreme freedom. Iodine, the companion element of bromine, was next thought of, but it was found impracticable to examine the substance in its usual solid condition. It however dissolves freely in bisulphide of carbon. There is no chemical union between the liquid and the iodine; it is simply a case of solution, in which the uncombined atoms of the element can act upon the radiant heat. When permitted to do so, it was found that a layer of dissolved iodine, sufficiently opaque to cut off the light of the midday sun, was almost absolutely transparent to the invisible calorific rays. [Footnote: Professor Dewar has recently succeeded in producing a medium highly opaque to light, and highly transparent to obscure heat, by fusing together sulphur and iodine.]
By prismatic analysis Sir William Herschel separated the luminous from the non-luminous rays of the sun, and he also sought to render the obscure rays visible by concentration. Intercepting the luminous portion of his spectrum he brought, by a converging lens, the ultra-red rays to a focus, but by this condensation he obtained no light. The solution of iodine offers a means of filtering the solar beam, or failing it, the beam of the electric lamp, which renders attainable far more powerful foci of invisible rays than could possibly be obtained by the method of Sir William Herschel. For to form his spectrum he was obliged to operate upon solar light which had passed through a narrow slit or through a small aperture, the amount of the obscure heat being limited by this circumstance. But with our opaque solution we may employ the entire surface of the largest lens, and having thus converged the rays, luminous and non-luminous, we can intercept the former by the iodine, and do what we please with the latter. Experiments of this character, not only with the iodine solution, but also with black glass and layers of lampblack, were publicly performed at the Royal Institution in the early part of 1862, and the effects at the foci of invisible rays, then obtained, were such as had never been witnessed previously.
In the experiments here referred to, glass lenses were employed to concentrate the rays. But glass, though highly transparent to the luminous, is in a high degree opaque to the invisible, heat-rays of the electric lamp, and hence a large portion of those rays was intercepted by the glass. The obvious remedy here is to employ rock-salt lenses instead of glass ones, or to abandon the use of lenses wholly, and to concentrate the rays by a metallic mirror. Both of these improvements have been introduced, and, as anticipated, the invisible foci have been thereby rendered more intense. The mode of operating remains however the same, in principle, as that made known in 1862. It was then found that an instant's exposure of the face of the thermoelectric pile to the focus of invisible rays, dashed the needles of a coarse galvanometer violently aside. It is now found that on substituting for the face of the thermo-electric pile a combustible body, the invisible rays are competent to set that body on fire.
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[6. Visible and Invisible Rays of the Electric Light.]
We have next to examine what proportion the non-luminous rays of the electric light bear to the luminous ones. This the opaque solution of iodine enables us to do with an extremely close approximation to the truth.
The pure bisulphide of carbon, which is the solvent of the iodine, is perfectly transparent to the luminous, and almost perfectly transparent to the dark, rays of the electric lamp. Supposing the total radiation of the lamp to pass through the transparent bisulphide, while through the solution of iodine only the dark rays are transmitted. If we determine, by means of a thermoelectric pile, the total radiation, and deduct from it the purely obscure, we obtain the value of the purely luminous emission. Experiments, performed in this way, prove that if all the visible rays of the electric light were converged to a focus of dazzling brilliancy, its heat would only be one-eighth of that produced at the unseen focus of the invisible rays.