This leads up to a few remarks upon the Voltaic battery. It is not my design to dwell upon the technical features of this wonderful instrument, but simply, by means of it, to show what varying shapes a given amount of energy can assume while maintaining unvarying quantitative stability. When that form of power which we call an electric current passes through Grove's battery, zinc is consumed in acidulated water; and in the battery we are able so to arrange matters that when no current passes no zinc shall be consumed. Now the current, whatever it may be, possesses the power of generating heat outside the battery. We can fuse with it iridium, the most refractory of metals, or we can produce with it the dazzling electric light, and that at any terrestrial distance from the battery itself.
We will now, however, content ourselves with causing the current to raise a given length of platinum wire, first to a blood-heat, then to redness, and finally to a white heat. The heat under these circumstances generated in the battery by the combustion of a fixed quantity of zinc is no longer constant, but it varies inversely as the heat generated outside. If the outside heat be nil, the inside heat is a maximum; if the external wire be raised to a blood-heat, the internal heat falls slightly short of the maximum. If the wire be rendered red-hot, the quantity of missing heat within the battery is greater, and if the external wire be rendered white-hot, the defect is greater still. Add together the internal and external heat produced by the combustion of a given weight of zinc, and you have an absolutely constant total. The heat generated without is so much lost within, the heat generated within is so much lost without, the polar changes already adverted to coming here conspicuously into play. Thus in a variety of ways we can distribute the items of a never-varying sum, but even the subtle agency of the electric current places no creative power in our hands.
Instead of generating external heat, we may cause the current to effect chemical decomposition at a distance from the battery. Let it, for example, decompose water into oxygen and hydrogen. The heat generated in the battery under these circumstances by the combustion of a given weight of zinc falls short of what is produced when there is no decomposition. How far short? The question admits of a perfectly exact answer. When the oxygen and hydrogen recombine, the heat absorbed in the decomposition is accurately restored, and it is exactly equal in amount to that missing in the battery. We may, if we like, bottle up the gases, carry in this form the heat of the battery to the polar regions, and liberate it there. The battery, in fact is a hearth on which fuel is consumed; but the heat of the combustion, instead of being confined in the usual manner to the hearth itself, may be first liberated at the other side of the world.
And here we are able to solve an enigma which long perplexed scientific men, and which could not be solved until the bearing of the mechanical theory of heat upon the phenomena of the Voltaic battery was understood. The puzzle was, that a single cell could not decompose water. The reason is now plain enough. The solution of an equivalent of zinc in a single cell develops not much more than half the amount of heat required to decompose an equivalent of water, and the single cell cannot cede an amount of force which it does not possess. But by forming a battery of two cells instead of one, we develop an amount of heat slightly in excess of that needed for the decomposition of the water. The two-celled battery is therefore rich enough to pay for that decomposition, and to maintain the excess referred to within its own cells.
Similar reflections apply to the thermo-electric pile, an instrument usually composed of small bars of bismuth and antimony soldered alternately together. The electric current is here evoked by warming the soldered junctions of one face of the pile. Like the Voltaic current, the thermo-electric current can heat wires, produce decomposition, magnetise iron, and deflect a magnetic needle at any distance from its origin. You will be disposed, and rightly disposed, to refer those distant manifestations of power to the heat communicated to the face of the pile, but the case is worthy of closer examination. In 1826 Thomas Seebeck discovered thermo-electricity, and six years subsequently Peltier made an observation which comes with singular felicity to our aid in determining the material used up in the formation of the thermo-electric current. He found that when a weak extraneous current was sent from antimony to bismuth the junction of the two metals was always heated, but that when the direction was from bismuth to antimony the junction was chilled. Now the current in the thermo-pile itself is always from bismuth to antimony, across the heated junction — a direction in which it cannot possibly establish itself without consuming the heat imparted to the junction. This heat is the nutriment of the current. Thus the heat generated by the thermo-current in a distant wire is simply that originally imparted to the pile, which has been first transmuted into electricity, and then retransmuted into its first form at a distance from its origin. As water in a state of vapour passes from a boiler to a distant condenser, and there assumes its primitive form without gain or loss, so the heat communicated to the thermo-pile distils into the subtler electric current, which is, as it were, recondensed into heat in the distant platinum wire.
In my youth I thought an electro-magnetic engine which was shown to me a veritable perpetual motion — a machine, that is to say, which performed work without the expenditure of power. Let us consider the action of such a machine. Suppose it to be employed to pump water from a lower to a higher level. On examining the battery which works the engine we find that the zinc consumed does not yield its full amount of heat. The quantity of heat thus missing within is the exact thermal equivalent of the mechanical work performed without. Let the water fall again to the lower level; it is warmed by the fall. Add the heat thus produced to that generated by the friction, mechanical and magnetical, of the engine; we thus obtain the precise amount of heat missing in the battery. All the effects obtained from the machine are thus strictly paid for; this 'payment for results' being, I would repeat, the inexorable method of nature.
No engine, however subtly devised, can evade this law of equivalence, or perform on its own account the smallest modicum of work. The machine distributes, but it cannot create. Is the animal body, then, to be classed among machines? When I lift a weight, or throw a stone, or climb a mountain, or wrestle with my comrade, am I not conscious of actually creating and expending force? Let us look at the antecedents of this force. We derive the muscle and fat of our bodies from what we eat. Animal heat you know to be due to the slow combustion of this fuel. My arm is now inactive, and the ordinary slow combustion of my blood and tissue is going on. For every grain of fuel thus burnt a perfectly definite amount of heat has been produced. I now contract my biceps muscle without causing it to perform external work. The combustion is quickened, and the heat is increased; this additional heat being liberated in the muscle itself. I lay hold of a 56 lb. weight, and by the contraction of my biceps lift it through the vertical space of a foot. The blood and tissue consumed during this contraction have not developed in the muscle their due amount of heat. A quantity of heat is at this moment missing in my muscle which would raise the temperature of an ounce of water somewhat more than one degree Fahrenheit. I liberate the weight: it falls to the earth, and by its collision generates the precise amount of heat missing in the muscle. My muscular heat is thus transferred from its local hearth to external space. The fuel is consumed in my body, but the heat of combustion is produced outside my body. The case is substantially the same as that of the Voltaic battery when it performs external work, or produces external heat. All this points to the conclusion that the force we employ in muscular exertion is the force of burning fuel and not of creative will. In the light of these facts the body is seen to be as incapable of generating energy without expenditure, as the solids and liquids of the Voltaic battery. The body, in other words, falls into the catagory of machines.
We can do with the body all that we have already done with the battery — heat platinum wires, decompose water, magnetise iron, and deflect a magnetic needle. The combustion of muscle may be made to produce all these effects, as the combustion of zinc may be caused to produce them. By turning the handle of a magneto-electric machine a coil of wire may be caused to rotate between the poles of a magnet. As long as the two ends of the coil are unconnected we have simply to overcome the ordinary inertia and friction of the machine in turning the handle. But the moment the two ends of the coil are united by a thin platinum wire a sudden addition of labour is thrown upon the turning arm. When the necessary labour is expended, its equivalent immediately appears. The platinum wire glows. You can readily maintain it at a white heat, or even fuse it. This is a very remarkable result. From the muscles of the arm, with a temperature of 100 degrees, we extract the temperature of molten platinum, which is nearly four thousand degrees. The miracle here is the reverse of that of the burning bush mentioned in Exodus. There the bush burned, but was not consumed — here the body is consumed, but does not burn. The similarity of the action with that of the Voltaic battery when it heats an external wire is too obvious to need pointing out. When the machine is used to decompose water, the heat of the muscle, like that of the battery, is consumed in molecular work, being fully restored when the gases recombine. As before, also, the transmuted heat of the muscles may be bottled up, carried to the polar regions, and there restored to its pristine form.
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The matter of the human body is the same as that of the world around us; and here we find the forces of the human body identical with those of inorganic nature. Just as little as the Voltaic battery is the animal body a creator of force. It is an apparatus exquisite and effectual beyond all others in transforming and distributing the energy with which it is supplied, but it possesses no creative power. Compared with the notions previously entertained regarding the play of 'Vital force' this is a great result. The problem of vital dynamics has been described by a competent authority as 'the grandest of all.' I subscribe to this opinion, and honour correspondingly the man who first successfully grappled with the problem. He was no pope, in the sense of being infallible, but he was a man of genius whose work will be held in honour as long as science endures I have already named him in connection with our illustrious countryman Dr. Joule. Other eminent men took up this subject subsequently and independently, but all that has been done hitherto enhances instead of diminishing the merits of Dr Mayer.