In all cases when the vapours of the liquids employed are sufficiently attenuated, no matter what the liquid may be, the visible action commences with the formation of a blue cloud. But here I must guard myself against all misconception as to the use of this term. The 'cloud' here referred to is totally invisible in ordinary daylight. To be seen, it requires to be surrounded by darkness, it only being illuminated by a powerful beam of light. This blue cloud differs in many important particulars from the finest ordinary clouds, and might justly have assigned to it an intermediate position between such clouds and true vapour. With this explanation, the term 'cloud,' or 'incipient cloud,' or 'actinic cloud,' as I propose to employ it, cannot, I think, be misunderstood.
I had been endeavouring to decompose carbonic acid gas by light. A faint bluish cloud, due it may be, or it may not be, to the residue of some vapour previously employed, was formed in the experimental tube. On looking across this cloud through a Nicol's prism, the line of vision being horizontal, it was found that when the short diagonal of the prism was vertical, the quantity of light reaching the eye was greater than when the long diagonal was vertical. When a plate of tourmaline was held between the eye and the bluish cloud, the quantity of light reaching the eye when the axis of the prism was perpendicular to the axis of the illuminating beam, was greater than when the axes of the crystal and of the beam were parallel to each other.
This was the result all round the experimental tube. Causing the crystal of tourmaline to revolve round the tube, with its axis perpendicular to the illuminating beam, the quantity of light that reached the eye was in all its positions a maximum. When the crystallographic axis was parallel to the axis of the beam, the quantity of light transmitted by the crystal was a minimum.
From the illuminated bluish cloud, therefore, polarised light was discharged, the direction of maximum polarisation being at right angles to the illuminating beam; the plane of vibration of the polarised light was perpendicular to the beam. [Footnote: This is still an undecided point; but the probabilities are so much in its favour, and it is in my opinion so much preferable to have a physical image on which the mind can rest, that I do not hesitate to employ the phraseology in the text.]
Thin plates of selenite or of quartz, placed between the Nicol and the actinic cloud, displayed the colours of polarised light, these colours being most vivid when the line of vision was at right angles to the experimental tube. The plate of selenite usually employed was a circle, thinnest at the centre, and augmenting uniformly in thickness from the centre outwards. When placed in its proper position between the Nicol and the cloud, it exhibited a system of splendidly-coloured rings.
The cloud here referred to was the first operated upon in the manner described. It may, however, be greatly improved upon by the choice of proper substances, and by the application, in proper quantities, of the substances chosen. Benzol, bisulphide of carbon, nitrite of amyl, nitrite of butyl, iodide of allyl, iodide of isopropyl, and many other substances may be employed. I will take the nitrite of butyl as illustrative of the means adopted to secure the best result, with reference to the present question.
And here it may be mentioned that a vapour, which when alone, or mixed with air in the experimental tube, resists the action of light, or shows but a feeble result of this action, may, when placed in proximity with another gas or vapour, exhibit vigorous, if not violent action. The case is similar to that of carbonic acid gas, which, diffused in the atmosphere, resists the decomposing action of solar light, but when placed in contiguity with chlorophyl in the leaves of plants, has its molecules shaken asunder.
Dry air was permitted to bubble through the liquid nitrite of butyl, until the experimental tube, which had been previously exhausted, was filled with the mixed air and vapour. The visible action of light upon the mixture after fifteen minutes' exposure was slight. The tube was afterwards filled with half an atmosphere of the mixed air and vapour, and a second half-atmosphere of air which had been permitted to bubble through fresh commercial hydrochloric acid. On sending the beam through this mixture, the tube, for a moment, was optically empty. But the pause amounted only to a small fraction of a second, a dense cloud being immediately precipitated upon the beam.
This cloud began blue, but the advance to whiteness was so rapid as almost to justify the application of the term instantaneous. The dense cloud, looked at perpendicularly to its axis, showed scarcely any signs of polarisation. Looked at obliquely the polarisation was strong.
The experimental tube being again cleansed and exhausted, the mixed air and nitrite-of-butyl vapour was permitted to enter it until the associated mercury column was depressed 1/10 of an inch. In other words, the air and vapour, united, exercised a pressure not exceeding 1/300th of an atmosphere. Air, passed through a solution of hydrochloric acid, was then added, till the mercury column was depressed three inches. The condensed beam of the electric light was passed for some time through this mixture without revealing anything within the tube competent to scatter the light. Soon, however, a superbly blue cloud was formed along, the track of the beam, and it continued blue sufficiently long to permit of its thorough examination. The light discharged from the cloud, at right angles to its own length, was at first perfectly polarised. It could be totally quenched by the Nicol. By degrees the cloud became of whitish blue, and for a time the selenite colours, obtained by looking at it normally, were exceedingly brilliant. The direction of maximum polarisation was distinctly at right angles to the illuminating beam. This continued to be the case as long as the cloud maintained a decided blue colour, and even for some time after the blue had changed to whitish blue. But, as the light continued to act, the cloud became coarser and whiter, particularly at its centre, where it at length ceased to discharge polarised light in the direction of the perpendicular, while it continued to do so at both ends.