Calcium Compounds.
The most important calcium compounds are lime and carbonate and phosphate of lime. Carbonate of lime is used as a pigment, and will be dealt with in detail among the mineral colours; it will be but briefly described here.
Calcium Oxide (Quicklime), CaO = 56.—When chalk and limestone, which consist of calcium carbonate, are heated, carbonic acid is evolved, and calcium oxide, commonly called quicklime, is left. For our purposes only very pure quicklime is to be used. Its ordinary impurities are iron oxide and magnesia: the former is found in lime made from red or brown limestone; the latter in lime made from dolomitic limestone. The presence of oxide of iron is recognised by the reddish tinge of the quicklime; if magnesia be present, a small quantity of the quicklime, when mixed with a very large quantity of water, leaves an insoluble residue which consists of magnesia.
When quicklime and water are brought together they unite very energetically and form calcium hydroxide or slaked lime. According to the quantity of water used for slaking, either dry slaked lime, lime paste, or milk of lime is produced, all of which find a use in colour making.
Calcium Hydroxide (Slaked Lime), Ca(OH)₂ = 74.—In order to prepare slaked lime, which contains lime united with just the necessary quantity of water, the pieces of quicklime are sprinkled with water from a watering can. The water is rapidly taken up and the sprinkling is repeated until the lumps begin to fall to a fine powder; in the process the lime becomes very hot. The slaked lime is then passed through a sieve in order to separate the larger pieces of quicklime which have not been slaked; the powder must be kept in well closed packages, since it energetically absorbs carbonic acid out of the air.
If so much water is added to the lime that a homogeneous wet mass is formed which can be readily moved with a shovel, one has then lime paste, which can be conveniently kept in pits as the masons do; it may be stored in this way for many months without appreciable alteration, still it is better to keep it covered. To prepare milk of lime, so much water is used in slaking that a milky liquid is formed, or the lime paste is mixed up in the proper quantity of water. Slaked lime dissolves in 700 to 800 parts of water; on standing, the undissolved slaked lime settles to the bottom of the milk of lime: thus it is better to prepare milk of lime immediately before use, and to stir it well to prevent the settling of the solid particles.
Slaked lime in one of its forms is often used instead of the more costly caustic soda in order to precipitate metallic oxides from their salts.
At times one finds a too strongly burnt lime, so-called “dead-burnt” lime, which is very slowly slaked by water. Such quicklime is slaked by allowing it to lie in water for days, or by means of hot water, which accomplishes the slaking more quickly.
Calcium Carbonate, CaCO₃ = 100, is found naturally in large quantities as chalk, which consists of the skeletons of extremely small animals. By powdering and levigating, it is converted into a soft powder, which is used to lighten the shade of lakes and other colours.
Calcium Sulphate (Gypsum), CaSO₄.2H₂O = 172.—This mineral, when finely powdered, is added to some colours.