Alumina plays a particularly important part in the manufacture of cobalt colours. When treated with a cobalt salt and heated it takes a fine blue shade.

In the foregoing those metals and their compounds have been treated which are extensively used in preparing colours without themselves forming coloured compounds. The chromates and prussiates are an exception to this. The ammonia compounds, the alkalis and alkaline earths, also the acids, are used in making many colours, although they do not contain colouring principles. The alumina compounds are in similar case. Themselves colourless, they form at the same time a carrier for the coloured compound and bring it into a suitable form for use as a pigment.

An example will explain what we mean by “carrier” of the colouring matter. Logwood contains a very handsome colouring matter which can be extracted by water. In order to be able to employ this colouring matter as a pigment it is combined with alumina, a compound insoluble in water being formed, which is called a lake. In this compound the alumina is to be regarded as the carrier of the colouring matter, which it has fixed in an insoluble form.

In dyeing, which in many respects is closely allied to colour making, the property of certain metallic compounds, themselves colourless, of fixing dyes is commonly utilised, the metallic compound being called the mordant. The fabric is first prepared with the metallic compound or mordant, and the colour then formed by bringing the mordanted material in contact with the colouring matter.

The “heavy metals” form, among their numerous compounds, a great number of coloured substances, and several of them are distinguished by a great wealth of coloured derivatives; for example, copper, chromium and cobalt form coloured compounds only. Although the use of pigments derived from the heavy metals has been considerably restricted in recent years by the discovery of a series of colouring matters which replace them, yet they are now, and always will be, of very great importance in the manufacture of colours. It is, therefore, necessary briefly to describe the various metals which are used in colour making, so that the manufacturer may know what metals produce harmless colours, permanent and unaltered by the atmosphere, and what do not.

The metals are divided into two great groups, designated, according to their specific gravities, the group of the light and of the heavy metals. The light metals comprise the alkali, alkaline earth and earth metals, whose important compounds we have just described. The specific gravity of each of these metals is less than five times that of water.

The heavy metals have a specific gravity exceeding 5; they are generally divided into groups, which are known by the name of the commonest metal in the group. These are as follows:—

Zinc groupZinc,Zn = 65.
Iron groupIron,Fe = 56.
Tungsten groupTungsten,W = 184.
Antimony groupAntimony,Sb = 120.
Tin groupTin,Sn = 119.
Lead groupLead,Pb = 207.
Silver groupSilver,Ag = 108.
Gold groupGold,Au = 197.
Platinum groupPlatinum,Pt = 194.

To the zinc group belong the metals zinc, cadmium and indium, of which only the two first are of importance here. The iron group comprises iron, manganese, cobalt, nickel, chromium and uranium, all of which are used in the manufacture of colours. The antimony group contains antimony and bismuth, the latter of which is of little importance. To the tin group belong tin and the rare metals titanium, zirconium, thorium, niobium and tantalum; of these tin alone is important in colour making. In the lead group are lead and thallium; lead produces many important pigments. The silver group contains silver, copper and mercury, the two latter of which are important. Of the gold group gold alone is of interest, and its importance has been diminished by the discovery of far cheaper substances which replace it. In the platinum group, which contains platinum, iridium, rhodium, ruthenium, palladium and osmium, only platinum itself is used as a colour; it is employed in porcelain painting to produce the peculiar metallic shimmer known technically as “lustre.”

The behaviour of the compounds, of the metals mentioned above towards sulphuretted hydrogen is of the greatest importance to the colour maker, since on it depends the alterability of the pigments when exposed to the atmosphere. Many metallic compounds are unaltered by the sulphuretted hydrogen present in the air, whilst others are in a high degree affected by it and become gradually darker, so that their colour may in the end approximate to black.