Lead Iodide.—On precipitating a solution of lead nitrate with potassium iodide, lead iodide is formed. This is but slightly soluble in water, and, when dry, has a handsome, deep yellow colour. Unfortunately it is not permanent, but is decomposed on exposure to light. It can be used for bronzing, but other and cheaper pigments are available for this purpose.
On account of the great solubility of lead iodide in a solution of potassium iodide, it is prepared in another way, and accurately weighed quantities are used. Calcium iodide may be used instead of the potassium salt; 100 parts of iodine, 15 parts of fine iron filings and 25 parts of lime are mixed with sufficient water to form a thin paste, which is warmed until all the iodine is dissolved, when water is added, the liquid filtered, and the residue washed in order to extract all the calcium iodide. The solution and wash waters are united, then a solution of 152 parts of lead acetate is added, when all the iodine is precipitated as lead iodide.
A simpler method is to dissolve equal parts of lead nitrate and potassium iodide separately, each in 20 parts of hot water, to mix the solutions and cool quickly, when lead iodide separates in very small crystals. When pure lead iodide is melted in the absence of air, and the fused mass powdered, a product of yet finer colour is formed. It is necessary to completely imbed the crucible in which the fusion is performed in the fire. The action of air on the melted mass would produce a basic iodide. The fine golden yellow colour of lead iodide adapts it especially for the production of gold bronzes on wall papers and fabrics.
Mars Yellow, which is generally reckoned among the best artists’ colours, is usually a mixture of ferric oxide and calcium sulphate or alumina. The pigment is prepared by mixing a solution of ferrous sulphate with milk of lime, when ferrous oxide is precipitated, which becomes yellowish brown on exposure to air, in consequence of the oxidation of the ferrous oxide. By heating the precipitate, according to the temperature different shades are obtained, varying between yellow and red. In addition to Mars yellow, Mars orange and Mars red are found in commerce.
The manufacture of this pigment is very simple: 1 part of ferrous sulphate is dissolved in 10 parts of water, and the solution mixed with milk of lime made from 1 part of quicklime and 40 parts of water. If it is desired to produce a darker shade, and especially a product to be afterwards converted into Mars orange, the amount of ferrous sulphate is increased to 2 parts. When the mixture has been made, it must be stirred for a long time, in order that the reacting substances may come thoroughly into contact. The precipitate, which at first is greenish grey, soon acquires by the action of the air the colour of ferric hydroxide, which becomes deeper on drying.
When dried and finely ground Mars yellow is heated in thin layers, it changes to dark yellow, and finally to orange red, a similar alteration taking place to that occurring when ferric hydroxide itself is heated.
A Mars yellow of a deeper shade, consisting of a mixture of ferric hydroxide and alumina, is obtained by precipitating with caustic soda a solution of ferrous sulphate and alum. The sodium sulphate which is formed at the same time must be removed as completely as possible by washing with boiling water.
By calcining Mars yellow for a long time at a high temperature, Mars brown is produced, a fine brown pigment. The value of Mars yellow and the pigments obtained from it lies not only in their fine shade, but in their permanence, which distinguishes the majority of the iron colours.
Siderin Yellow.—This not very handsome yellow consists of ferric chromate; it is obtained by adding a neutral solution of ferric chloride to a strong boiling solution of potassium bichromate so long as a precipitate is formed. Siderin yellow is said to be used both in oil and water, and to be particularly adapted for use in sodium silicate paints, since in the course of time it forms a stony mass with that substance.
The low price of iron salts would make it desirable to employ chromates of iron, but it appears to be difficult to obtain a compound of constant composition. In experiments with this object the author did not succeed in obtaining products of the same shade. Others have probably been equally unsuccessful, for siderin yellow has never been used in quantity, as it would have been were there no difficulties in the way of its preparation.