Vogel’s Iron Red.—This preparation, which is particularly brilliant and therefore highly suitable for an artists’ colour, is made by adding a saturated solution of oxalic acid to a boiling solution of green vitriol. The greenish yellow precipitate of ferrous oxalate is collected on a filter and well washed with water. After drying, the precipitate is heated in a shallow iron dish to a temperature of 200° C., at which the ferrous oxalate decomposes and is converted into a soft fiery red powder consisting of pure ferric oxide. By igniting this powder in covered crucibles the different shades of ferric oxide can be obtained.
Macay’s English Red.—Seven hundred and four parts of ferrous sulphate, 1,000 parts of copper chloride, and 1,678 parts of common salt are dissolved, the solution boiled and the precipitate ignited.
In the manufacture of fuming or Nordhausen sulphuric acid, ferric oxide is obtained as a residue. It is then known under the names of English red, caput mortuum, colcothar, rouge and Indian red as a very cheap pigment. It is also used as a polishing material. Fuming sulphuric acid is made by heating green vitriol at a white heat in retorts placed in furnaces; sulphur dioxide and trioxide are evolved, whilst in the retorts there remains a residue of almost pure ferric oxide, containing small quantities of basic ferric sulphate, which can only be decomposed by long continued violent heating. The vapours of sulphur trioxide are caught in receivers containing oil of vitriol, in which they dissolve and produce fuming sulphuric acid.
The residue in the retorts, which has only a low commercial value, can be converted into a good pigment without the expenditure of much money or labour. It is ground in mills as finely as possible, and, if necessary, afterwards levigated. The fine powder is mixed with varying quantities of common salt, the object of which is to prevent the temperature from rising too high in the calcining process. Common salt is volatile at a temperature approaching a strong red heat; when the temperature has once risen so far, a further rise is prevented by the heat taken up in volatilising the salt. In order to make ferric oxide of a yellow tinge, 2 per cent. of salt are added, and the mixture heated with a moderate fire for 1 hour. To obtain the deeper shades, the addition of common salt is increased even to 6 per cent. For a brownish-red oxide, 4 per cent. of salt are added and the mixture heated for 4 hours; for a dark violet oxide, 6 per cent. of salt are used, and the mixture is heated for 6 hours with the fiercest fire.
It has been observed that the shade of the product is finer the more completely air is excluded from the glowing mass and the more quickly the product, after sufficient heating, is cooled down to the ordinary temperature.
Fire-clay tubes are used for heating the ferric oxide, which are similar to gas retorts, and are built one above the other in furnaces. The number in one furnace may reach 60. Each retort is closed by a well-fitting lid, which is luted with clay after the retorts are filled, a small opening being left through which the heated air may escape. If the retorts were closed completely air-tight they would burst on heating.
Ferric oxide pigments are made in very large quantity by several works, which bring up to 20 different shades, varying from reddish yellow to dark violet, into the market.
On account of their great resistance to the action of the atmosphere and of chemical agents, the ferric oxide pigments are particularly suitable for painting iron and other metals which are exposed to air or water. They are also suited to fresco work.
Lower qualities of iron reds are made by calcining ochres, large deposits of which occur in nature, and also from the residues of basic ferric sulphate obtained in the alum manufacture. These varieties are at the best usable for ordinary painting, but never for artists’ pigments.
According to the method of Steinau, iron pigments can be made from wrought-iron scraps, turnings, etc., by causing them to rust through alternate contact with air and water. The resulting ferric hydrate is either at once used as a pigment or converted into other shades by calcining. By heating in the air a red pigment is formed; by heating with coal in the absence of air a black; and from mixtures of red and black different shades of brown. If the iron turnings can be obtained cheap, this process should be well adapted to the manufacture of fine iron pigments.