Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances

by Joseph Black

PART II.

In reflecting afterwards upon these experiments, an explication of the nature of lime offered itself, which seemed to account, in an easy manner, for most of the properties of that substance.

It is sufficiently clear, that the calcarious earths in their native state, and that the alkalis and magnesia in their ordinary condition, contain a large quantity of fixed air, and this air certainly adheres to them with considerable force, since a strong fire is necessary to separate it from magnesia, and the strongest is not sufficient to expel it entirely from fixed alkalis, or take away their power of effervescing with acid salts.

These considerations led me to conclude, that the relations between fixed air and alkaline substances was somewhat similar to the relation between these and acids; that as the calcarious earths and alkalis attract acids strongly and can be saturated with them, so they also attract fixed air, and are in their ordinary state saturated with it: and when we mix an acid with an alkali or with an absorbent earth, that the air is then set at liberty, and breaks out with violence; because the alkaline body attracts it more weakly than it does the acid, and because the acid and air cannot both be joined to the same body at the same time.

I also imagined, that, when the calcarious earths are exposed to the action of a violent fire, and are thereby converted into quick-lime, they suffer no other change in their composition than the loss of a small quantity of water and of their fixed air. The remarkable acrimony which we perceive in them after this process, was not supposed to proceed from any additional matter received in the fire, but seemed to be an essential property of the pure earth, depending on an attraction for those several substances which it then became capable of corroding or dissolving, which attraction had been insensible as long as the air adhered to the earth, but discovered itself upon the separation.

This supposition was founded upon an observation of the most frequent consequences of combining bodies in chemistry. Commonly when we join two bodies together, their acrimony or attraction for other substances becomes immediately either less perceivable or entirely insensible; altho' it was sufficiently strong and remarkable before their union, and may be rendered evident again by disjoining them. A neutral salt, which is composed of an acid and alkali, does not possess the acrimony of either of its constituent parts. It can easily be separated from water, has little or no effect upon metals, is incapable of being joined to inflammable bodies, and of corroding and dissolving animals and vegetables; so that the attraction both of the acid and alkali for these several substances seems to be suspended till they are again separated from one another.

Crude lime was therefore considered as a peculiar acrid earth rendered mild by its union with fixed air: and quick-lime as the same earth, in which, by having separated the air, we discover that acrimony or attraction for water, for animal, vegetable, and for inflammable substances.

That the calcarious earths really lose a large quantity of air when they are burnt to quick-lime, seems sufficiently proved by an experiment of Mr. Margraaf,[6] an exceedingly accurate and judicious Chemist. He subjected eight ounces of osteocolla to distillation in an earthen retort, finishing his process with the most violent fire of a reverberatory, and caught in the receiver only two drams of water, which by its smell and properties shewed itself to be slightly alkaline. He does not tell us the weight of the osteocolla remaining in the retort, and only says, that it was converted into quick-lime; but as no calcarious earth can be converted into quick-lime, or bear the heat which he applied without losing above a third of its weight, we may safely conclude, that the loss in his experiment was proportional, and proceeded chiefly from the dissipation of fixed air.

According to our theory, the relation of the calcarious earth to air and water appeared to agree with the relation of the same earth to the vitriolic and vegetable acids. As chalk for instance has a stronger attraction for the vitriolic than for the vegetable acid, and is dissolved with more difficulty when combined with the first, than when joined to the second: so it also attracts air more strongly than water, and is dissolved with more difficulty when saturated with air than when compounded with water only.