Flies and spiders die in acid air, but not so quickly as in nitrous air. This surprized me very much; as I had imagined that nothing could be more speedily fatal to all animal life than this pure acid vapour.
As inflammable air, I have observed, fires at one explosion in the vapour of smoking spirit of nitre, just like an equal mixture of inflammable and common air, I thought it was possible that the fume which naturally rises from common spirit of salt might have the same effect, but it had not. For this purpose I treated the spirit of salt, as I had before done the smoking spirit of nitre; first filling a phial with it, then inverting it in a vessel containing a quantity of the same acid; and having thrown the inflammable air into it, and thereby driven out all the acid, turning it with its mouth upwards, and immediately applying a candle to it.
Acid air not being so manageable as most of the other kinds of air, I had recourse to the following peculiar method, in order to ascertain its specific gravity. Having filled an eight ounce phial with this air, and corked it up, I weighed it very accurately; and then, taking out the cork, I blew very strongly into it with a pair of bellows, that the common air might take place of the acid; and after this I weighed it again, together with the cork, but I could not perceive the least difference in the weight. I conclude, however, from this experiment, that the acid air is heavier than the common air, because the mouth of the phial and the inside of it were evidently moistened by the water which the acid vapour had attracted from the air, which moisture must have added to the weight of the phial.
SECTION V.
Of Inflammable Air.
It will have appeared from my former experiments, that inflammable air consists chiefly, if not wholly, of the union of an acid vapour with phlogiston; that as much of the phlogiston as contributes to make air inflammable is imbibed by the water in which it is agitated; that in this process it soon becomes fit for respiration, and by the continuance of it comes at length to extinguish flame. These observations, and others which I have made upon this kind of air, have been confirmed by my later experiments, especially those in which I have connected electrical experiments with those on air.
The electric spark taken in any kind of oil produces inflammable air, as I was led to observe in the following manner. Having found, as will be mentioned hereafter, that ether doubles the quantity of any kind of air to which it is admitted; and being at that time engaged in a course of experiments to ascertain the effect of the electric matter on all the different kinds of air, I had the curiosity to try what it would do with common air, thus increased by means of ether. The very first spark, I observed, increased the quantity of this air very considerably, so that I had very soon six or eight times as much as I began with; and whereas water imbibes all the ether that is put to any kind of air, and leaves it without any visible change, with respect to quantity or quality, this air, on the contrary, was not imbibed by water. It was also very little diminished by the mixture of nitrous air. From whence it was evident, that it had received an addition of some other kind of air, of which it now principally consisted.
In order to determine whether this effect was produced by the wire, or the cement by which the air was confined (as I thought it possible that phlogiston might be discharged from them) I made the experiment in a glass syphon, fig. 19, and by that means I contrived to make the electric spark pass from quicksilver through the air on which I made the experiment, and the effect was the same as before. At one time there happened to be a bubble of common air, without any ether, in one part of the syphon, and another bubble with ether in another part of it; and it was very amusing to observe how the same electric sparks diminished the former of these bubbles, and increased the latter.