Thus far, as you see, we are merely reviving in a different association the old ideas of Buffon. But just at this point comes in a new conception, which gives far greater grandeur to our modern theory: for we conceive that those smallest particles in which the qualities of a substance inhere are definite bodies or systems of bodies moving in space, and that a lump of sugar is a universe of moving worlds.
If on a clear night you direct a telescope to one of the many star-clusters of our northern heavens, you will have presented to the eye as good a diagram as we can at present draw of what we suppose would, under certain circumstances, be seen in a lump of sugar if we could look into the molecular universe with the same facility with which the telescope penetrates the depths of space.
Do you tell me that the absurdities of Buffon were wisdom when compared with such wild speculations as these? The criticism is simply what I expected, and I must remind you that, as I intimated at the outset, this conception of modern science is in the transition period of which I then spoke, and, although very familiar to scientific scholars, has not yet been grasped by the popular mind. I can further only add that, wild as it may appear, the idea is the growth of legitimate scientific investigation, and express my conviction that it will soon become as much a part of the popular belief as those grand conceptions of astronomy to which I have referred.
Do you rejoin that we can see the suns in a stellar cluster, but can not even begin to see the molecules? I must again remind you that, in fact, you only see points of light in the field of the telescope, and that your knowledge that these points are immensely distant suns is an inference of astronomical science; and, further, that our knowledge—if I may so call our confident belief—that the lump of sugar is an aggregate of moving molecules is an equally legitimate inference of molecular mechanics, a science which, although so much newer, is as positive a field of study as astronomy. Moreover, sight is not the only avenue to knowledge; and, although our material limitations forbid us to expect that the microscope will ever be able to penetrate the molecular universe, yet we feel assured that we have been able by strictly experimental methods to weigh molecular masses and measure molecular magnitudes with as much accuracy as those of the fixed stars.
Of all forms of matter the gas has the simplest molecular structure, and, as might be anticipated, our knowledge of molecular magnitudes is as yet chiefly confined to materials of this class. I have given below some of the results which have been obtained in regard to the molecular magnitudes of hydrogen gas, one of the best studied of this class of substances; and, although the vast numbers are as inconceivable as are those of astronomy, they can not fail to impress you with the reality of the magnitudes they represent. I take hydrogen gas for my illustration rather than air, because our atmosphere is a mixture of two gases, oxygen and nitrogen, and therefore its condition is less simple than that of a perfectly homogeneous material like hydrogen. The molecular dimensions of other substances, although varying very greatly in their relative values, are of the same order of magnitude as these.[A]
Dimension of Hydrogen Molecules calculated for Temperature of Melting Ice, and for the Mean Height of the Barometer of the Sea Level:
Mean velocity, 6,099 feet a second.
Mean path, 31 ten-millionths of an inch.
Collisions, 17,750 millions each second.
Diameter, 438,000, side by side, measure 1⁄100 of an inch.
Mass, 14 (millions3) weigh 1⁄1000 of a grain.
Gas-volume, 311 (millions3) fill one cubic inch.
To explain how the values here presented were obtained would be out of place in a popular lecture,[B] but a few words in regard to two or three of the data are required to elucidate the subject of this lecture.
First, then, in regard to the mass or weight of the molecules. So far as their relative values are concerned, chemistry gives us the means of determining the molecular weights with very great accuracy; but when we attempt to estimate their weights in fractions of a grain—the smallest of our common standards—we can not expect precision, simply because the magnitudes compared are of such a different order; and the same is true of most of the other absolute dimensions, such as the diameter and volume of the molecules. We only regard the values given in our table as a very rough estimate, but still we have good grounds for believing that they are sufficiently accurate to give us a true idea of the order of the quantities with which we are dealing; and it will be seen that, although the numbers required to express the relations to our ordinary standards are so large, these molecular magnitudes are no more removed from us on the one side than are those of astronomy on the other.