Scientific Culture, and Other Essays / Second Edition; with Additions

by Jr. Josiah P. Cooke

But if this investigation of gas and vapor densities brought a great strain upon the dualistic system, the second of the three great investigations of Dumas, to which we have referred, led to its complete overthrow. The experimental results of this investigation would not be regarded at the present day as remarkable, and can not be compared either in breadth or intricacy with the results of numerous investigations of a similar character which have since been made. The most important of these results were the substitution products obtained by the action of chlorine gas on acetic acid. They were published in a series of papers entitled "Sur les Types Chimiques," and the capital point made was that chlorine could be substituted in acetic acid for a large part of the hydrogen without destroying the acid relations of the product; and the inference was, that the qualities of a compound substance depend not simply on the nature of the elements of which it consists, but also on the manner or type according to which these elements are combined.

To the chemists of the present day these results and inferences seem so natural that it is difficult to understand the spirit with which they were received forty years ago. But it must be remembered that at that time the conceptions of chemists were wholly molded in the dualistic system. It was thought that chemical action depended upon the antagonism between metals and metalloids, bases and acids, acid salts and basic salts, and that the qualities of the products resulted from the blending of such opposite virtues. That chlorine should unite with hydrogen was natural, for no two substances could be more unlike; but that chlorine should supply the place of hydrogen in a chemical compound was a conception which the dualists scouted as absurd. Even Liebig, the "father of organic chemistry," warmly controverted the interpretation which Dumas had given to the facts he had discovered. Liebig himself had successfully investigated the chemical relations of a large class of organic products. He had, however, worked on the lines of the dualistic system, showing that organic substances might be classed with similar inorganic substances, if we assume that certain groups of atoms, which he called "compound radicals," might take the place of elementary substances. In the edition of the organic part of Turner's "Chemistry" bearing his name, organic chemistry is defined as the "chemistry of compound radicals," and the formulas of organic compounds are represented on the dualistic system. Liebig's conceptions were therefore naturally opposed to those advanced by Dumas; but it is pleasant to know that the controversy which arose never disturbed the friendly relations between these two noble men of science, who could approach the same truth from different sides, and yet have faith that each was working for the same great end. In his commemorative address on Pelouze, Dumas expresses toward Liebig sentiments of affectionate regard, and Liebig dedicates to Dumas, with equal warmth, the German edition of his "Letters on Chemistry."

By the second investigation, as by the first, although Dumas gave a most fruitful conception to chemistry, he only took the first step in developing it. His conception of chemical types was very indefinite, and Laurent wrote of it, a few years later: "Dumas's theory is too general; by its poetic coloring, it lends itself to false interpretations; it is a programme of which we await the realization." Laurent himself helped toward this realization, and in his early death left the work to his associate and friend Gerhardt, who pushed it forward with great zeal, classifying chemical compounds according to the four types of hydrochloric acid, water, ammonia, and marsh-gas. Hofmann, Williamson, Wurtz, and many others, greatly aided in this work by realizing many of the possibilities which these types suggested; and thus modern Structural Chemistry gradually grew up, in which the types of Dumas and Gerhardt have been in their turn superseded by the larger views which the doctrine of quantivalence has opened out to the scientific imagination. It is a singular fact, however, that, while the growth began in France, the harvest has been chiefly reaped by Germans; and that, although in its inception the movement was strongly opposed in Germany, its legitimate conclusions are now repudiated by the most influential school of French chemists.

The third great investigation of Dumas was his revision of the atomic weights of many of the chemical elements, and in none of his work did he show greater experimental skill. His determination of the atomic weight of oxygen by the synthesis of water, and of that of carbon by the synthesis of carbonic dioxide, are models of quantitative experimental work. To this investigation, as to all his other work, Dumas was directed by his vivid scientific imagination. In his teaching, from the first, he had aimed to exhibit the relations of the elementary substances by classing them in groups of allied bodies; and at the meeting of the British Association in 1851 he had delighted the chemical section by the eloquence and force with which he exhibited such relations, especially triads of elementary substances; such as chlorine, bromine, and iodine; oxygen, sulphur, and selenium; phosphorus, arsenic, and antimony; calcium, barium, and strontium: in which not only the atomic weight, but also the qualities of the middle member of the triad, were the mean of those of the other two members. Later, he came to regard these triads as parts of more extended series, in each of which the atomic weights increased from the first to the last element of the series, by determinate, but not always by equal differences, the values being, if not exact multiples of the hydrogen atom according to the hypothesis of Prout, at least multiples of one half or one quarter of that weight. There can be no doubt that these speculations were more fanciful than sound, and that Dumas did not do full justice to earlier theories of the same kind; but with him these speculations were merely the ornaments, not the substance of his work, and they led him to fix more accurately the constants of chemistry, and thus to lay a trustworthy foundation upon which the superstructure of science could safely be built.

That exuberance of fancy to which we have referred made Dumas one of the most successful of teachers, and one of the most fascinating of lecturers. It was the privilege of the writer to attend the larger part of two of his courses of lectures given in Paris, in the winters of 1848 and 1851, and he remembers distinctly the impression produced. Besides the well-arranged material and the carefully prepared experiment, there was an elegance and pomp of circumstance which added greatly to the effect. The large theatre of the Sorbonne was filled to overflowing long before the hour. The lecturer always entered at the exact moment, in full evening dress, and held to the end of a two hours' lecture the unflagging attention of his audience. The manipulations were entirely left to the care of a number of assistants, who brought each experiment to a conclusion at the exact moment when the illustration was required. An elegance of diction, an appropriateness of illustration, and a beauty of exposition, which could not be excelled, were displayed throughout, and the enthusiasm of a French audience added to the animation of the scene.

To the writer the lectures of Dumas were brought in contrast to those of Faraday. Both were perfect of their kind, but very different. Faraday's method was far more simple and natural, and he excelled Dumas in bringing home to young minds abstruse truths by the logic of well-arranged consecutive experiment. With Dumas there was no attempt to popularize science; he excelled in clearness and elegance of exposition. He exhausted the subject which he treated, and was able to throw a glow of interest around details which by most teachers would have been made dry and profitless.

Two volumes of Dumas's lectures have been published; one comprises his course on the "Philosophy of Chemistry," delivered at the College of France in 1836; the other contains only a single lecture, accompanied by notes, entitled "The Balance of Organic Life," which was delivered at the Medical School of Paris, August 20, 1841. In both these volumes will be found the beauty of exposition and the elegance of diction of which we have spoken, and they are models of literary style. But of course the sympathetic enthusiasm of the great man's presence can not be reproduced by written words.

The lecture on "The Balance of Organic Life" was probably the most remarkable of Dumas's literary efforts. It dealt simply with the relations which the vegetable sustains to the animal kingdom through the atmosphere, which, though now so familiar, were then not generally understood; and the late Dr. Jeffries Wyman, who heard the lecture, always spoke of it with the greatest enthusiasm.

As might be expected, Dumas's oratory found an ample field in the Chamber of Deputies and in the Senate; and whether setting forth a project of recasting the copper coinage or a law of drainage, or ridiculing the absurd theories of homœopathy, he riveted the attention of his colleagues as completely as he had entranced the students at the Sorbonne.

In the early part of his life, Dumas was a voluminous writer, and in 1828 published the "Traité de Chimie appliquée aux Arts," in eight large octavo volumes, with an atlas of plates in quarto. But besides this extended treatise, the two volumes of lectures just referred to are his only important literary works. He published numerous papers in scientific journals, which, as we have seen, produced a most marked effect on the growth of chemical science. But the number of his monographs is not large compared with those of many of his contemporaries, and his work is to be judged by its importance and influence rather than by the extent of the field which it covers.