This sum, which is the mechanical energy of the system, is therefore an invariable quantity in all the states to which it may be brought by the interaction of its various parts, and the word energy well expresses a capital property of this quantity. For if two systems are connected in such a way that any change produced in the one necessarily brings about a change in the other, there can be no variation in the characteristic quantity of the second except so far as the characteristic quantity of the first itself varies—on condition, of course, that the connexions are made in such a manner as to introduce no new force. It will thus be seen that this quantity well expresses the capacity possessed by a system for modifying the state of a neighbouring system to which we may suppose it connected.
Now this theorem of pure mechanics was found wanting every time friction took place—that is to say, in all really observable cases. The more perceptible the friction, the more considerable the difference; but, in addition, a new phenomenon always appeared and heat was produced. By experiments which are now classic, it became established that the quantity of heat thus created independently of the nature of the bodies is always (provided no other phenomena intervene) proportional to the energy which has disappeared. Reciprocally, also, heat may disappear, and we always find a constant relation between the quantities of heat and work which mutually replace each other.
It is quite clear that such experiments do not prove that heat is work. We might just as well say that work is heat. It is making a gratuitous hypothesis to admit this reduction of heat to mechanism; but this hypothesis was so seductive, and so much in conformity with the desire of nearly all physicists to arrive at some sort of unity in nature, that they made it with eagerness and became unreservedly convinced that heat was an active internal force.
Their error was not in admitting this hypothesis; it was a legitimate one since it has proved very fruitful. But some of them committed the fault of forgetting that it was an hypothesis, and considered it a demonstrated truth. Moreover, they were thus brought to see in phenomena nothing but these two particular forms of energy which in their minds were easily identified with each other.
From the outset, however, it became manifest that the principle is applicable to cases where heat plays only a parasitical part. There were thus discovered, by translating the principle of equivalence, numerical relations between the magnitudes of electricity, for instance, and the magnitudes of mechanics. Heat was a sort of variable intermediary convenient for calculation, but introduced in a roundabout way and destined to disappear in the final result.
Verdet, who, in lectures which have rightly remained celebrated, defined with remarkable clearness the new theories, said, in 1862: "Electrical phenomena are always accompanied by calorific manifestations, of which the study belongs to the mechanical theory of heat. This study, moreover, will not only have the effect of making known to us interesting facts in electricity, but will throw some light on the phenomena of electricity themselves."
The eminent professor was thus expressing the general opinion of his contemporaries, but he certainly seemed to have felt in advance that the new theory was about to penetrate more deeply into the inmost nature of things. Three years previously, Rankine also had put forth some very remarkable ideas the full meaning of which was not at first well understood. He it was who comprehended the utility of employing a more inclusive term, and invented the phrase energetics. He also endeavoured to create a new doctrine of which rational mechanics should be only a particular case; and he showed that it was possible to abandon the ideas of atoms and central forces, and to construct a more general system by substituting for the ordinary consideration of forces that of the energy which exists in all bodies, partly in an actual, partly in a potential state.
By giving more precision to the conceptions of Rankine, the physicists of the end of the nineteenth century were brought to consider that in all physical phenomena there occur apparitions and disappearances which are balanced by various energies. It is natural, however, to suppose that these equivalent apparitions and disappearances correspond to transformations and not to simultaneous creations and destructions. We thus represent energy to ourselves as taking different forms—mechanical, electrical, calorific, and chemical—capable of changing one into the other, but in such a way that the quantitative value always remains the same. In like manner a bank draft may be represented by notes, gold, silver, or bullion. The earliest known form of energy, i.e. work, will serve as the standard as gold serves as the monetary standard, and energy in all its forms will be estimated by the corresponding work. In each particular case we can strictly define and measure, by the correct application of the principle of the conservation of energy, the quantity of energy evolved under a given form.
We can thus arrange a machine comprising a body capable of evolving this energy; then we can force all the organs of this machine to complete an entirely closed cycle, with the exception of the body itself, which, however, has to return to such a state that all the variables from which this state depends resume their initial values except the particular variable to which the evolution of the energy under consideration is linked. The difference between the work thus accomplished and that which would have been obtained if this variable also had returned to its original value, is the measure of the energy evolved.
In the same way that, in the minds of mechanicians, all forces of whatever origin, which are capable of compounding with each other and of balancing each other, belong to the same category of beings, so for many physicists energy is a sort of entity which we find under various aspects. There thus exists for them a world, which comes in some way to superpose itself upon the world of matter—that is to say, the world of energy, dominated in its turn by a fundamental law similar to that of Lavoisier. [5] This conception, as we have already seen, passes the limit of experience; but others go further still. Absorbed in the contemplation of this new world, they succeed in persuading themselves that the old world of matter has no real existence and that energy is sufficient by itself to give us a complete comprehension of the Universe and of all the phenomena produced in it. They point out that all our sensations correspond to changes of energy, and that everything apparent to our senses is, in truth, energy. The famous experiment of the blows with a stick by which it was demonstrated to a sceptical philosopher that an outer world existed, only proves, in reality, the existence of energy, and not that of matter. The stick in itself is inoffensive, as Professor Ostwald remarks, and it is its vis viva, its kinetic energy, which is painful to us; while if we possessed a speed equal to its own, moving in the same direction, it would no longer exist so far as our sense of touch is concerned.