Among the gases most difficult to liquefy, hydrogen has been the object of particular research and of really quantitative experiments. Its properties in a liquid state are now very clearly known. Its boiling-point, measured with a helium thermometer which has been compared with thermometers of oxygen and hydrogen, is -252°; its critical temperature is -241° C.; its critical pressure, 15 atmospheres. It is four times lighter than water, it does not present any absorption spectrum, and its specific heat is the greatest known. It is not a conductor of electricity. Solidified at 15° absolute, it is far from reminding one by its aspect of a metal; it rather resembles a piece of perfectly pure ice, and Dr Travers attributes to it a crystalline structure. The last gas which has resisted liquefaction, helium, has recently been obtained in a liquid state; it appears to have its boiling-point in the neighbourhood of 6° absolute. [11]
§ 3. SOLIDS AND LIQUIDS
The interest of the results to which the researches on the continuity between the liquid and the gaseous states have led is so great, that numbers of scholars have naturally been induced to inquire whether something analogous might not be found in the case of liquids and solids. We might think that a similar continuity ought to be there met with, that the universal character of the properties of matter forbade all real discontinuity between two different states, and that, in truth, the solid was a prolongation of the liquid state.
To discover whether this supposition is correct, it concerns us to compare the properties of liquids and solids. If we find that all properties are common to the two states we have the right to believe, even if they presented themselves in different degrees, that, by a continuous series of intermediary bodies, the two classes might yet be connected. If, on the other hand, we discover that there exists in these two classes some quality of a different nature, we must necessarily conclude that there is a discontinuity which nothing can remove.
The distinction established, from the point of view of daily custom, between solids and liquids, proceeds especially from the difficulty that we meet with in the one case, and the facility in the other, when we wish to change their form temporarily or permanently by the action of mechanical force. This distinction only corresponds, however, in reality, to a difference in the value of certain coefficients. It is impossible to discover by this means any absolute characteristic which establishes a separation between the two classes. Modern researches prove this clearly. It is not without use, in order to well understand them, to state precisely the meaning of a few terms generally rather loosely employed.
If a conjunction of forces acting on a homogeneous material mass happens to deform it without compressing or dilating it, two very distinct kinds of reactions may appear which oppose themselves to the effort exercised. During the time of deformation, and during that time only, the first make their influence felt. They depend essentially on the greater or less rapidity of the deformation, they cease with the movement, and could not, in any case, bring the body back to its pristine state of equilibrium. The existence of these reactions leads us to the idea of viscosity or internal friction.
The second kind of reactions are of a different nature. They continue to act when the deformation remains stationary, and, if the external forces happen to disappear, they are capable of causing the body to return to its initial form, provided a certain limit has not been exceeded. These last constitute rigidity.
At first sight a solid body appears to have a finite rigidity and an infinite viscosity; a liquid, on the contrary, presents a certain viscosity, but no rigidity. But if we examine the matter more closely, beginning either with the solids or with the liquids, we see this distinction vanish.
Tresca showed long ago that internal friction is not infinite in a solid; certain bodies can, so to speak, at once flow and be moulded. M.W. Spring has given many examples of such phenomena. On the other hand, viscosity in liquids is never non-existent; for were it so for water, for example, in the celebrated experiment effected by Joule for the determination of the mechanical equivalent of the caloric, the liquid borne along by the floats would slide without friction on the surrounding liquid, and the work done by movement would be the same whether the floats did or did not plunge into the liquid mass.
In certain cases observed long ago with what are called pasty bodies, this viscosity attains a value almost comparable to that observed by M. Spring in some solids. Nor does rigidity allow us to establish a barrier between the two states. Notwithstanding the extreme mobility of their particles, liquids contain, in fact, vestiges of the property which we formerly wished to consider the special characteristic of solids.