If the liquid, instead of being a solvent like pure water, contains an electrolyte, it already contains metallic ions, the osmotic pressure of which will be opposite to that of the solution. Three cases may then present themselves—either there will be equilibrium, or the electrostatic attraction will oppose itself to the pressure of solution and the metal will be negatively charged, or, finally, the attraction will act in the same direction as the pressure, and the metal will become positively and the solution negatively charged. Developing this idea, Professor Nernst calculates, by means of the action of the osmotic pressures, the variations of energy brought into play and the value of the differences of potential by the contact of the electrodes and electrolytes. He deduces this from the electromotive force of a single battery cell which becomes thus connected with the values of the osmotic pressures, or, if you will, thanks to the relation discovered by Van t' Hoff, with the concentrations. Some particularly interesting electrical phenomena thus become connected with an already very important group, and a new bridge is built which unites two regions long considered foreign to each other.
The recent discoveries on the phenomena produced in gases when rendered conductors of electricity almost force upon us, as we shall see, the idea that there exist in these gases electrified centres moving through the field, and this idea gives still greater probability to the analogous theory explaining the mechanism of the conductivity of liquids. It will also be useful, in order to avoid confusion, to restate with precision this notion of electrolytic ions, and to ascertain their magnitude, charge, and velocity.
The two classic laws of Faraday will supply us with important information. The first indicates that the quantity of electricity passing through the liquid is proportional to the quantity of matter deposited on the electrodes. This leads us at once to the consideration that, in any given solution, all the ions possess individual charges equal in absolute value.
The second law may be stated in these terms: an atom-gramme of metal carries with it into electrolysis a quantity of electricity proportionate to its valency. [19]
Numerous experiments have made known the total mass of hydrogen capable of carrying one coulomb, and it will therefore be possible to estimate the charge of an ion of hydrogen if the number of atoms of hydrogen in a given mass be known. This last figure is already furnished by considerations derived from the kinetic theory, and agrees with the one which can be deduced from the study of various phenomena. The result is that an ion of hydrogen having a mass of 1.3 x 10^-20 grammes bears a charge of 1.3 X 10^-20 electromagnetic units; and the second law will immediately enable the charge of any other ion to be similarly estimated.
The measurements of conductivity, joined to certain considerations relating to the differences of concentration which appear round the electrode in electrolysis, allow the speed of the ions to be calculated. Thus, in a liquid containing 1/10th of a hydrogen-ion per litre, the absolute speed of an ion would be 3/10ths of a millimetre per second in a field where the fall of potential would be 1 volt per centimetre. Sir Oliver Lodge, who has made direct experiments to measure this speed, has obtained a figure very approximate to this. This value is very small compared to that which we shall meet with in gases.
Another consequence of the laws of Faraday, to which, as early as 1881, Helmholtz drew attention, may be considered as the starting-point of certain new doctrines we shall come across later.
Helmholtz says: "If we accept the hypothesis that simple bodies are composed of atoms, we are obliged to admit that, in the same way, electricity, whether positive or negative, is composed of elementary parts which behave like atoms of electricity."
The second law seems, in fact, analogous to the law of multiple proportions in chemistry, and it shows us that the quantities of electricity carried vary from the simple to the double or treble, according as it is a question of a uni-, bi-, or trivalent metal; and as the chemical law leads up to the conception of the material atom, so does the electrolytic law suggest the idea of an electric atom.