The experiences just cited have not been reproduced, in spite of numerous attempts to this end. It cannot therefore be considered as proved that zinc sulphide and calcium sulphide are capable of emitting, under the action of light, invisible rays which traverse black paper and act on photographic plates.
M. Becquerel has made similar experiments on the salts of uranium, some of which are fluorescent.
He obtained photographic impressions through black paper with the double sulphate of uranium and potassium.
M. Becquerel at first believed that this salt, which is fluorescent, behaved like the sulphides of zinc and calcium in the experiments of MM. Henry, Niewenglowski, and Troost. But the conclusion of his experiments showed that the phenomenon observed was in no way related to the fluorescence. It is not necessary that the salt should be fluorescent; further, uranium and all its compounds, fluorescent or not, act in the same manner, and metallic uranium is the most active. M. Becquerel finally found that by placing uranium compounds in complete darkness, they continue acting on photographic plates through black paper for years. M. Becquerel allows that uranium and its compounds emit peculiar rays—uranium rays. He proved that these rays can penetrate thin metallic screens, and that they discharge electrified bodies. He also made experiments from which he concluded that uranium rays undergo reflection, refraction, and polarisation.
The work of other physicists (Elster and Geitel, Lord Kelvin, Schmidt, Rutherford, Beattie, and Smoluchowski) confirms and extends the results of the researches of M. Becquerel, with the exception of those relating to the reflection, refraction, and polarisation of uranium rays, which in this respect behave like Röntgen rays, as has been recognised first by Mr. Rutherford and then by M. Becquerel himself.
CHAPTER I.
Radio-activity of Uranium and Thorium. Radio-active Minerals.
Becquerel Rays.—The uranium rays discovered by M. Becquerel act upon photographic plates screened from the light; they can penetrate all solid, liquid, and gaseous substances, provided that the thickness is sufficiently reduced; in passing through a gas, they cause it to become a feeble conductor of electricity.
These properties of the uranium compounds are not due to any known cause. The radiation seems to be spontaneous; it loses nothing in intensity, even on keeping the compounds in complete darkness for several years; hence there is no question of the phosphorescence being specially produced by light.
The spontaneity and persistence of the uranium radiation appear as a quite unique physical phenomenon. M. Becquerel kept a piece of uranium for several years in the dark, and he has affirmed that at the end of this time the action upon a photographic plate had not sensibly altered. MM. Elster and Geitel made a similar experiment, and also found the action to remain constant.
I measured the intensity of radiation of uranium by the effect of this radiation on the conductivity of air. The method of measurement will be explained later. I also obtained figures which prove the persistence of radiation within the limits of accuracy of the experiments.