The absorptive property however is partial: an absorptive substance either cuts off a portion of the light of a fluorescent spectrum or stripes it with dark lines: each substance absorbs rays peculiar to itself. Those employed by Professor Stokes were the alkaloids and glucosides, and he assumed the spectrum of tin for their examination because it has a long interval of continuity.
The fluorescent property of yellow uranite was discovered by Professor Stokes some years ago, and now he has added another fluorescent mineral in adularia or moonstone; from its natural faces and planes of cleavage alike a beautiful blue fluorescence emanated under the induction spark. As the same was observed in colourless felspars generally, Professor Stokes concluded that fluorescence is an inherent property in the silicate of alumina and potash constituting the crystal of moonstone. The blue fluorescence extended to a very sensible though small depth within the substance.
A particular variety of fluor spar found at Alston Moor in Cumberland, which is very pale by transmitted light, shows a strong blue fluorescence, and is eminently phosphorescent on exposure to the electric spark. It is the same kind of crystal in which Sir David Brewster originally discovered the property of fluorescence. On presenting such a crystal to the spark passing between aluminium terminals, besides the usual blue fluorescence, there was another of a reddish colour extending not near so far into the crystal, produced by the rays belonging to the strong lines of aluminium of extreme refrangibility.
The cube of fluor spar which showed these effects was externally colourless to the depth of 1⁄20 of an inch; then came one or two strata parallel to the faces of the cube showing the ruddy fluorescence, while the blue fluorescence extended to a much greater depth and had a stratified appearance. This crystal was eminently phosphorescent, its blue phosphorescence being arranged in strata parallel to the face of the cube like the blue fluorescence, but it was not perceptible beyond a very moderate distance below the surface at which the exciting cause entered, that cause being the photographic rays of extremely high refrangibility of the electric spark—taken, as in all these experiments, between the secondary terminals of an induction coil in connection with the coatings of a Leyden jar, and refracted by quartz prisms.
Mr. Stokes has employed fluorescence as a means of tracing substances in impure chemical solutions. When a pure fluorescent substance is examined in a pure spectrum it is found that on passing from the extreme red to the violet and beyond, the fluorescence commences at a certain point of the spectrum, varying from one substance to another, and continues from thence onwards more or less strongly in one part or another according to the particular substance. The colour of the fluorescent light is found to be nearly constant throughout the spectrum. ‘Hence when in a solution examined in a pure spectrum we notice the fluorescence taking as it were a fresh start with a different colour, we may be pretty sure that we have to deal with a mixture of two fluorescent substances.’
Experience as well as theory shows that rapid absorption is accompanied by copious fluorescence. But experience has hitherto also shown what could not have been predicted, and may not be universally true, that conversely absorption is accompanied in the case of a fluorescent substance by fluorescence.
The phosphorescent light of insects, fish, and plants is owing to chemical action, which produces many luminous phenomena; but a great number of inorganic and organic substances shine in the dark with a phosphorescence which is nearly allied to fluorescence. It is produced by exposure to the sun, by heat, electricity, insulation, cleavage, friction, and motion. For if a bottle containing nitrate of uranium be shaken, it shines spontaneously with a vivid light; even the hand shows phosphorescence in the dark after being exposed to the sun.
The essential difference between fluorescence and phosphorescence consists in the time during which the light lasts. Fluorescence ceases almost immediately after the exciting cause is withdrawn, while a phosphorescent body whether excited by heat, solar light, or electricity, lasts a much longer time; besides, the fluorescent rays are generally of lower refrangibility. Light and heat are temporarily absorbed and given out again by every body on the surface of the earth, more or less, that are exposed to the sun’s light. The nights would be much darker even when illuminated by the stars were it not for earth light, for the molecules restore to the ether, in the form of phosphorescence, the undulations they have received from the sun’s light during the day. The snow and ice blink of the sailors is a striking instance; generally, however, it is of much shorter duration. The phosphorescent property is nearly allied to electricity, for bodies that are bad conductors are apt to become phosphorescent, while good conductors of electricity rarely if ever show it. Ozone must be phosphorescent, for oxygen exhibits persistent light when electric discharges are sent through it, and Mr. Faraday saw a flash of lightning leave a luminous trace on a cloud which lasted for a short time.
In the solar spectrum the chemical or actinic rays produce phosphorescence, which the red rays have the power to extinguish. M. Nièpce de St-Victor found that solar light impresses its vibrations so strongly on substances exposed for a short time to its influence that they not only shine in the dark, but that the phosphorescent light they radiate has chemical energy enough to decompose substances in unstable equilibrium, and leave daguerreotype impressions of great delicacy and beauty.
The polarization of light and heat affords a remarkable instance of the elective power of matter. Light and heat are said to be polarized, which, having been once reflected, are rendered incapable of being again reflected at certain angles. For example, a ray incident on a plate of flint glass at an angle of 57° is rendered totally incapable of being reflected at that same angle from another plate of flint glass in a plane at right angles to the first. At the incidence of 57° the whole of the ray is polarized: it is the maximum of polarization for flint glass, but there is a partial polarization for every other angle; the portion of the ray polarized increases gradually up to the maximum, as the incidence approaches to 57°. All reflecting surfaces are capable of polarizing light and heat, but the angle of incidence at which the ray is totally polarized is different in each substance. Thus, the angle of incidence for the maximum polarization of crown glass is 56° 55ʹ, and no ray can be totally polarized by reflection from the surface of water unless the angle of incidence is 53° 11ʹ. As each substance has its own maximum polarizing angle, the effect is evidently owing to the action of the molecules of matter, and not to any peculiarity in the light or heat.[[8]]