VII
THE SCIENCE OF LIGHT-PRODUCTION
In previous chapters much of the historical development of artificial lighting has been presented and several subjects have been traced to the modern period which marks the beginning of an intensive attack by scientists upon the problems pertaining to the production of efficient and adequate light-sources. Many historical events remain to be touched upon in later chapters, but it is necessary at this point for the reader to become acquainted with certain general physical principles in order that he may read with greater interest some of the chapters which follow. It is seen that from a standpoint of artificial lighting, the "dark age" extended well into the nineteenth century. Oil-lamps and gas-lighting began to be seriously developed at the beginning of the last century, but the pioneers gave attention chiefly to mechanical details and somewhat to the chemistry of the fuels. It was not until the science of physics was applied to light-sources that rapid progress was made.
All the light-sources used throughout the ages, and nearly all modern ones, radiate light by virtue of the incandescence of solids or of solid particles and it is an interesting fact that carbon is generally the solid which emits light. This is due to various physical characteristics of carbon, the chief one being its extremely high melting-point. However, most practicable light-sources of the past and present may be divided into two general classes: (1) Those in which solids or solid particles are heated by their own combustion, and (2) those in which the solids are heated by some other means. Some light-sources include both principles and some perhaps cannot be included under either principle without qualification. The luminous flames of burning material such as those of wood-splinters, candles, oil-lamps, and gas-jets, and the glowing embers of burning material appear in the first class; and incandescent gas-mantles, electric filaments, and arc-lamps to some extent are representative of the second class. Certain "flaming" arcs involve both principles, but the light of the firefly, phosphorescence, and incandescent gas in "vacuum" tubes cannot be included in this simplified classification. The status of these will become clear later.
It has been seen that flames have been prominent sources of artificial light; and although of low luminous efficiency, they still have much to commend them from the standpoints of portability, convenience, and subdivision. The materials which have been burned for light, whether solid or liquid, are rich in carbon, and the solid particles of carbon by virtue of their incandescence are responsible for the brightness of a flame. A jet of pure hydrogen gas will burn very hot but with so low a brightness as to be barely visible. If solid particles are injected into the flame, much more light usually will be emitted. A gas-burner of the Bunsen type, in which complete combustion is obtained by mixing air in proper proportions with the gas, gives a hot flame which is of a pale blue color. Upon the closing of the orifice through which air is admitted, the flame becomes bright and smoky. The flame is now less hot, as indicated by the presence of smoke or carbon particles, and combustion is not complete. However, it is brighter because the solid particles of carbon in passing upward through the flame become heated to temperatures at which they glow and each becomes a miniature source of light.
A close observer will notice that the flame from a match, a candle, or a gas-jet, is not uniformly bright. The reader may verify this by lighting a match and observing the flame. There is always a bluish or darker portion near the bottom. In this less luminous part the air is combining with the hydrogen of the hydrocarbon which is being vaporized and disintegrated. Even the flame of a candle or of a burning splinter is a miniature gas-plant, for the solid or liquid hydrocarbons are vaporized before being burned. Owing to the incoming colder air at this point, the flame is not hot enough for complete combustion. The unburned carbon particles rise in its draft and become heated to incandescence, thus accounting for the brighter portion. In cases of complete combustion they are eventually oxidized into carbon dioxide before they are able to escape. If a piece of metal be held in the flame, it immediately becomes covered with soot or carbon, because it has reduced the temperature below the point at which the chemical reaction—the uniting of carbon with oxygen—will continue. An ordinary flat gas-flame of the "bats-wing" type may vary in temperature in its central portion from 300°F. at the bottom to about 3000°F. at the top. The central portion lies between two hotter layers in which the vertical variation is not so great. The brightness of the upper portion is due to incandescent carbon formed in the lower part.
When scientists learned by exploring flames that brightness was due to the radiation of light by incandescent solid matter, the way was open for many experiments. In the early days of gas-lighting investigations were made to determine the relation of illuminating value to the chemical constitution of the gas. The results combined with a knowledge of the necessity for solid carbon in the flame led to improvements in the gas for lighting purposes. Gas rich in hydrocarbons which in turn are rich in carbon is high in illuminating value. Heating-effect depends upon heat-units, so the rating of gas in calories or other heat-units per cubic foot is wholly satisfactory only for gas used for heating. The chemical constitution is a better indicator of illuminating value.
As scientific knowledge increased, efforts were made to get solid matter into the flames of light-sources. Instead of confining efforts to the carbon content of the gas, solid materials were actually placed in the flame, and in this manner various incandescent burners were developed. A piece of lime placed in a hydrogen flame or that of a Bunsen burner is seen to become hot and to glow brilliantly. By producing a hotter flame by means of the blowpipe, in which hydrogen and oxygen are consumed, the piece of lime was raised to a higher temperature and a more intense light was obtained. In Paris there was a serious attempt at street-lighting by the use of buttons of zirconia heated in an oxygen-coal-gas flame, but it proved unsuccessful owing to the rapid deterioration of the buttons. This was the line of experimentation which led to the development of the lime-light. The incandescent burner was widely employed, and until the use of electricity became common the lime-light was the mainstay for the stage and for the projection of lantern slides. It is in use even to-day for some purposes. The origin of the phrase "in the lime-light" is obvious. The luminous intensity of the oxyhydrogen lime-light as used in practice was generally from 200 to 400 candle-power. The light decreases rapidly as the burner is used, if a new surface of lime is not presented to the flame from time to time. At the high temperatures the lime is somewhat volatile and the surface seems to change in radiating power. Zirconium oxide has been found to serve better than lime.
Improvements were made in gas-burners in order to obtain hotter flames into which solid matter could be introduced to obtain bright light. Many materials were used, but obviously they were limited to those of a fairly high melting-point. Lime, magnesia, zirconia, and similar oxides were used successfully. If the reader would care to try an experiment in verification of this simple principle, let him take a piece of magnesium ribbon such as is used in lighting for photography and ignite it in a Bunsen flame. If it is held carefully while burning, a ribbon of ash (magnesia) will be obtained intact. Placing this in the faintly luminous flame, he will be surprised at the brilliance of its incandescence when it has become heated. The simple experiment indicates the possibilities of light-production in this direction. Naturally, metals of high melting-point such as platinum were tried and a network of platinum wire, in reality a platinum mantle, came into practical use in about 1880. The town of Nantes was lighted by gas-burners using these platinum-gauze mantles, but the mantles were unsuccessful owing to their rapid deterioration. This line of experimentation finally bore fruit of immense value for from it the gas-mantle evolved.
A group of so-called "rare-earths," among which are zirconia, thoria, ceria, erbia, and yttria (these are oxides of zirconium, etc.) possess a number of interesting chemical properties some of which have been utilized to advantage in the development of modern artificial light. They are white or yellowish-white oxides of a highly refractory character found in certain rare minerals. Most of them are very brilliant when heated to a high temperature. This latter feature is easily explained if the nature of light and the radiating properties of substances are considered. Suppose pieces of different substances, for example, glass and lime, are heated in a Bunsen flame to the same temperature which is sufficiently great to cause both of them to glow. Notwithstanding the identical conditions of heating, the glass will be only faintly luminous, while the piece of lime will glow brilliantly. The former is a poor radiator; furthermore, the lime radiates a relatively greater percentage of its total energy in the form of luminous energy.