A gas which has played a prominent part in lighting is acetylene, produced by the interaction of water and calcium carbide. No other gas easily produced upon a commercial scale yields as much light, volume for volume, as acetylene. It has the great advantage of being easily prepared from raw material whose yield of gas is considerably greater for a given amount than the raw materials which are used in making other illuminating gases. The simplicity of the manufacture of acetylene from calcium carbide and water gives to this gas a great advantage in some cases. It has served for individual lighting in houses and in other places where gas or electric service was unavailable. Where space is limited it also had an advantage and was adopted to some extent on automobiles, motor-boats, ships, lighthouses, and railway cars before electric lighting was developed for these purposes.
The color of the acetylene flame is satisfactory and it is extremely brilliant compared with most flames. An interesting experiment is found in placing a spark-gap in the flame and sending a series of sparks across it. If the conditions are proper the flame will became very much brighter. When the gas issues from a proper jet under sufficient pressure, the flame is quite steady. Its luminous efficiency gives it an advantage over other open gas-flames in lighting rooms, because for the same amount of light it vitiates the air and exhausts the oxygen to a less degree than the others. Of course, in these respects the gas-mantle is superior.
The reaction which takes place when water and calcium carbide are brought together is a double decomposition and is represented by,
CaC2 + H2O = C2H2 + CaO
It will be seen that the products are acetylene gas and calcium oxide or lime. The lime, being hydroscopic and being in the presence of water or water-vapor in the acetylene generator, really becomes calcium hydroxide Ca(OH)2, commonly called slaked lime. If there are impurities in the calcium carbide, it is sometimes necessary to purify the gas before it may be safely used for interior lighting.
The burners and mantles used in acetylene lighting are essentially the same as those for other gas-lighting, excepting, of course, that they are especially adapted for it in minor details.
The chief source of calcium carbide in this country is the electric furnace. Cheap electrical energy from hydro-electric developments, such as the Niagara plants, have done much to make the earth yield its elements. Aluminum is very prevalent in the soil of the earth's surface, because its oxide, alumina, is a chief constituent of ordinary clay. But the elements, aluminum and oxygen, cling tenaciously to each other and only the electric furnace with its excessively high temperatures has been able to separate them on a large commercial scale. Similarly, calcium is found in various compounds over the earth's surface. Limestone abounds widely, hence the oxide and carbonate of lime are wide-spread. But calcium clings tightly to the other elements of its compounds and it has taken the electric furnace to bring it to submission. The cheapness of calcium carbide is due to the development of cheap electric power. It is said that calcium carbide was discovered as a by-product of the electric furnace by accidentally throwing water upon the waste materials of a furnace process. The discovery of a commercial scale of manufacture of calcium carbide has been a boon to isolated lighting. Electric lighting has usurped its place on the automobile and is making inroads in country-home lighting. Doubtless, acetylene will continue to serve for many years, but its future does not appear as bright as it did many years ago.
The Pintsch gas, used to some extent in railroad passenger-cars in this country, is an oil-gas produced by the destructive distillation of petroleum or other mineral oil in retorts heated externally. The product consists chiefly of methane and heavy hydrocarbons with a small amount of hydrogen. In the early days of railways, some trains were not run after dark and those which were operated were not always lighted. At first attempts were made at lighting railway cars with compressed coal-gas, but the disadvantage of this was the large tank required. Obviously, a gas of higher illuminating-value per volume was desired where limited storage space was available, and Pintsch turned his attention to oil-gas. Gas suffers in illuminating-value upon being compressed, but oil-gas suffers only about half the loss that coal-gas does. In about 1880 Pintsch developed a method of welding cylinders and buoys which satisfied lighthouse authorities and he was enabled to furnish these filled with compressed gas. Thus the buoy was its own gas-tank. He devised lanterns which would remain lighted regardless of wind and waves and thus gained a start with his compressed-gas systems. He compressed the gas to a pressure of about one hundred and fifty pounds per square inch and was obliged to devise a reducer which would deliver the gas to the burner at about one pound per square inch. This regulator served well throughout many years of exacting service. The system began to be adopted on ships and railroads in 1880 and for many years it has served well.
Although gas-lighting has affected the activities of mankind considerably by intensifying commerce and industry and by advancing social progress, the illuminants which eventually took the lead have extended the possibilities and influences of artificial light. In the brief span of a century civilized man is almost totally independent of natural light in those fields over which he has control. What another century will bring can be predicted only from the accomplishments of the past. These indicate possibilities beyond the powers of imagination.