HISTORY OF PHOSPHORUS
The “cold light” produced by phosphorus caused it to be considered a miraculous chemical for a long time after its discovery, about 1669. During the intervening three centuries numerous other chemical miracles have been found, yet phosphorus retains a special aura of universal importance in chemistry. Many investigators have occupied themselves with this element and its diverse chemical compounds. Further enlightenment and insight into the ways of nature can be expected from these efforts.
Not only is the story of phosphorus a major drama in the history of chemistry; it also illustrates, in a spectacular example, the growth of this science through the discovery of connections between apparently unrelated phenomena, and the continuous interplay between basic science and the search for practical usage.
The Author: Eduard Farber is a research professor at American University, Washington, D.C., and has been associated with the Smithsonian Institution as a consultant in chemistry.
When phosphorus was discovered, nearly three centuries ago, it was considered a miraculous thing. The only event that provoked a similar emotion was the discovery of radium more than two centuries later. The excitement about the Phosphorus igneus, Boyle’s Icy Noctiluca, was slowly replaced by, or converted into, chemical research. Yet, if we would allow room for emotion in research, we could still be excited about the wondrous substance that chemical and biological work continues to reveal as vitally important. It is a fundamental plant nutrient, an essential part in nerve and brain substance, a decisive factor in muscle action and cell growth, and also a component in fast-acting, powerful poisons. The importance of phosphorus was gradually recognized and the means by which this took place are characteristic and similar to other developments in the history of science. This paper was written in order to summarize these various means which led to the highly complex ways of present research.
The Element from Animals and Plants
It was a little late to search for the philosophers’ stone in 1669, yet it was in such a search that phosphorus was discovered. Wilhelm Homberg (1652-1715) described it in the following manner: Brand, “a man little known, of low birth, with a bizarre and mysterious nature in all he did, found this luminous matter while searching for something else. He was a glassmaker by profession, but he had abandoned it in order to be free for the pursuit of the philosophical stone with which he was engrossed. Having put it into his mind that the secret of the philosophical stone consisted in the preparation of urine, this man worked in all kinds of manners and for a very long time without finding anything. Finally, in the year 1669, after a strong distillation of urine, he found in the recipient a luminant matter that has since been called phosphorus. He showed it to some of his friends, among them Mister Kunkel [sic].”[1]
Neither the name nor the phenomenon were really new. Organic phosphorescent materials were known to Aristotle, and a lithophosphorus was the subject of a book published in 1640, based on a discovery made by a shoemaker, Vicenzo Casciarolo, on a mountain-side near Bologna in 1630.[2] Was the substance new which Brand showed to his friends? Johann Gottfried Leonhardi quotes a book of 1689 in which the author, Kletwich, claims that this phosphorus had already been known to Fernelius, the court physician of King Henri II of France (1154-1189).[3] To the same period belongs the “Ordinatio Alchid Bechil Saraceni philosophi,” in which Ferdinand Hoefer found a distillation of urine with clay and carbonaceous material described, and the resulting product named escarbuncle.[4] It would be worth looking for this source; although Bechil would still remain an entirely unsuccessful predecessor, it does seem strange that in all the distillations of arbitrary mixtures, the conditions should never before 1669 have been right for the formation and the observation of phosphorus.