Figure 11.—Dipping of matchsticks in France, about 1870. The frame which holds the matches so that one end protrudes at the bottom, is lowered over a pan containing molten sulfur. The sulfur-covered matches are then dropped into a phosphorous paste. See [figure 12]. (From Figuier, Merveilles de l’industrie, volume 3, 1874, page 575.)
Figure 12.—Pan for dipping matchsticks into phosphorus paste, about 1870. The letters on the picture are: A, matches; B, water bath; C, frame; D, plate; E, phosphorus paste; F, oven. The phosphorus paste of Böttger, 1842, contained 10 phosphorus, 25 antimony sulfide, 12.5 manganese dioxide, 15 gelatin. According to Figuier (page 579), R. Wagner substituted lead dioxide for the manganese dioxide. (From Figuier, volume 3, 1874, page 576.)
In the system of chemistry, as it developed in the first half of the 19th century, the new development can be characterized as the turn from inorganic to organic phosphates, from the substance of minerals and strong chemical interactions to the components in which phosphate groups remained combined with carbon-containing substances.