Ans. If the plates be connected by a wire outside the electrolyte, the tendency which dissimilar electrical charges have to neutralize one another causes a flow of negative electricity through the wire from zinc to copper, and a positive flow in the opposite direction. The “static” charge being thus disposed of, a fresh charge is given to the plates by the action of the acid, which commences to dissolve the zinc. As long as the wire connects the copper and zinc plates, the acid will continue its action on the zinc until either acid or zinc is exhausted.
The reader may ask: how can there be a positive flow when both plates are negatively electrified?
An analogy is the best way to make this point clear: Imagine two equal vessels, from each of which the air has been partially exhausted, but from one (A) 10 times as much air has been taken as from the other (B). Connect A and B by a tube. Now, although both vessels have less than the atmospheric pressure, that is, both have “negative” pressures, yet a current of air will flow from B to A until the pressures in each are equalized; that is, until both have equal “negative charges” of air.
There is a second important effect of the acid solution or electrolyte in a cell. If pure sulphuric acid were used, the first action or production of an electrical charge on the zinc plate would be the same, but when the plates were joined by the wire the current would soon cease. The reason for this lies in the fact that the sulphate of zinc, which is the compound produced by the acid plus the zinc, being insoluble in pure undiluted sulphuric acid, remains on the surface of the zinc plate. The coating of sulphate of zinc thus formed also operates as a protective agent, and no further electrical charge can be induced until it is removed. The addition of water to the acid has the effect of allowing the sulphate of zinc to dissolve, and the zinc plate is left free for further action.
Ques. What governs the rate of current flow of a primary cell?
Ans. The size of the elements and their proximity.
Effects of Polarization.—The film of hydrogen bubbles affects the strength of the current of the cell in two ways:
1. It weakens the current by the increased resistance which it offers to the flow, for bubbles of gas are bad conductors;
2. It weakens the current by setting up an opposing electromotive force.
Hydrogen is almost as oxidizable a substance as zinc, especially when freshly deposited (in the “nascent” state), and is electro-positive; hence, the hydrogen itself produces a difference of potential, which would tend to start a current in the opposite direction to the true zinc-to-copper current. It is therefore an important matter to abolish this polarization, otherwise the currents furnished by batteries would not be constant.