According to the theory proposed by Sir Ernest Rutherford, in order to account for the phenomena of scattering of
-rays, the atom consists of a central positively charged nucleus surrounded by a cluster of electrons. The nucleus is the seat of the essential part of the mass of the atom, and has linear dimensions exceedingly small compared with the distances apart of the electrons in the surrounding cluster. From the results of experiments on scattering of alpha rays, Rutherford concluded that the charge on the nucleus corresponds to a number of electrons per atom approximately equal to half the atomic weight. Concordant evidence from a large number of very different phenomena has led to the more definite assumption that the number of electrons per atom is exactly equal to the atomic number, i.e., the number of the corresponding element in the periodic table. This view was first proposed by van den Broek[3]. While the nucleus theory has been of great utility in explaining many important properties of the atom[4], on the other hand it is evident that it is impossible by its aid to explain many other fundamental properties if we base our considerations on the ordinary electrodynamical theory; but this can hardly be considered as a valid objection at the present time. It does not seem that there is any escape from the conclusion that it is impossible to account for the phenomena of temperature radiation on ordinary electrodynamics, and that the modification to be introduced in this theory must be essentially equivalent with the assumptions first used by Planck in the deduction of his radiation formula[5]. These assumptions are known as the Quantum theory. In my previous paper it was attempted to apply the main principles of this theory by introducing the following general assumptions:—
A. An atomic system possesses a number of states in which no emission of energy radiation takes place, even if the particles are in motion relative to each other, and such an emission is to be expected on ordinary electrodynamics. The states are denoted as the “stationary” states of the system under consideration.
B. Any emission or absorption of energy radiation will correspond to the transition between two stationary states. The radiation emitted during such a transition is homogeneous and the frequency
is determined by the relation
where