is a whole number,

the frequency of vibration of the oscillator, and

is Planck's constant.

If we attempt to use this result to explain the spectra of the elements, however, we encounter difficulties, because the motion of the particles in the atom, in spite of its simple structure, is in general exceedingly complicated compared with the motion of a Planck oscillator. The question then arises, how Planck's result ought to be generalized in order to make its application possible. Different points of view immediately suggest themselves. Thus we might regard this equation as a relation expressing certain characteristic properties of the distinctive motions of an atomic system and try to obtain the general form of these properties. On the other hand, we may also regard equation (1) as a statement about a property of the process of radiation and inquire into the general laws which control this process.

In Planck's theory it is taken for granted that the frequency of the radiation emitted and absorbed by the oscillator is equal to its own frequency, an assumption which may be written

if in order to make a sharp distinction between the frequency of the emitted radiation and the frequency of the particles in the atoms, we here and in the following denote the former by