In 1909 Paschen succeeded in observing the first two lines of this series corresponding to

.

The part played by hydrogen in the development of our knowledge of the spectral laws is not solely due to its ordinary simple spectrum, but it can also be traced in other less direct ways. At a time when Rydberg's laws were still in want of further confirmation Pickering (1897) found in the spectrum of a star a series of lines whose wave lengths showed a very simple relation to the ordinary hydrogen spectrum, since to a very close approximation they could be expressed by the formula

Rydberg considered these lines to represent a new series of lines in the spectrum of hydrogen, and predicted according to his theory the existence of still another series of hydrogen lines the wave lengths of which would be given by

By examining earlier observations it was actually found that a line had been observed in the spectrum of certain stars which coincided closely with the first line in this series (corresponding to