1. Temperature. Have a battery thermometer (Figure 37) on hand, and measure the temperature of the electrolyte of each cell on the line. If you note that some particular cell is running hotter than the others, keep the thermometer in that cell and watch the temperature. Do not let the temperature rise above 110 degrees Fahrenheit, except for a very short time. Should the highest of the temperature of the cells rise above 110 degrees, reduce the charging rate.
2. Gassing. Near the end of a charge and when the specific gravity has stopped rising, or is rising very slowly, bubbles of gas will rise from the electrolyte, this being due to the charging current decomposing the water of the electrolyte into hydrogen and oxygen. If this gassing is too violent, a considerable amount of active material will be blown from the plates. Therefore, when this gassing begins, the charging rate should be reduced, unless the entire charging has been done at a low rate, say about five amperes.
If gassing begins in any cell soon after the charge is started, or before the specific gravity has reached its highest point, reduce the charging rate to eliminate the gassing.
If one battery or one cell shows a high temperature and the others do not, or begins gassing long before the others do, remove that battery from the charging line for further investigation and replace it with another so as not to slow up the charge of the other batteries which are acting normally.
As long as excessive temperatures and too-early gassing are avoided, practically any charging rate may be used, especially at the start. With a constant potential charging set, as shown in Figure 48, the charge may start at as high a rate as 50 amperes. If this system of charging is used, the temperature must be watched very carefully and gassing must be looked for. With the usual series method of charging, a charge may, in an emergency, be started at 20 amperes or more. As a general rule do not use a higher rate than 10 amperes. A five ampere rate is even better, but more time will be required for the charge.
Time Required for a Charge. The time required is not determined by the clock, but by the battery. Continue the charge until each cell is gassing freely (not violently) and for five hours after the specific gravity has stopped rising. The average condition of batteries brought in for charge permits them to be fully charged in about 48 hours, the time being determined as stated above. Some batteries may charge fully in less time, and some may require from four days to a week, depending entirely upon the condition of the batteries. Do not give any promise as to when a recharge battery will be ready. No one can tell how long it will take to charge.
Specific Gravity at the End of the Charge. The specific gravity of the electrolyte in a fully charged cell should be from 1.280 to 1.300. If it varies more than 10 points above or below these values, adjust it by drawing off some of the electrolyte with a hydrometer and adding water to lower the gravity, or 1.400 acid to raise the gravity. After adjusting the gravity charge for one hour more.
Battery Voltage at End of Charge. The voltage of a fully charged cell is from 2.5 to 2.7 when the temperature of the electrolyte is 80 degrees Fahrenheit; 2.4 to 2.6 when the temperature of the electrolyte is 100 degrees Fahrenheit, and 2.35 to 2.55 volts when the temperature of the electrolyte is 120 degrees Fahrenheit, and this voltage, together with hydrometer readings of 1.280-1.300 indicate that the battery is fully charged.
Just before putting a battery which has been charged into service, give it a 15 seconds high rate discharge test, see page 266.
Painting. Before returning a battery to the owner wipe it perfectly clean and dry. Then wipe the covers, terminals, connectors and handles with a rag wet with ammonia. Next give the case a light coat of black paint which may be made by mixing lamp black and shellac. This paint dries in about five minutes and gives a good gloss. The customer may not believe that you are returning the battery which he brought in but he will most certainly be pleased with your service and will feel that if you take such pains with the outside of his battery you will certainly treat the inside with the same care when repairs are necessary. The light coat of paint costs very little for one battery, but may bring you many dollars worth of work.