If you can detect a vinegar-like odor rising from the vent holes, you may be absolutely sure that the separators used in that battery have developed acetic acid due to not having received the proper treatment necessary to prepare them for use in the battery. The electrolyte should be dumped from such a battery immediately and the battery should be filled and rinsed with water several times. Then the battery should be opened without loss of time, to see whether, by removing the separators and washing the plates thoroughly, the plates may be saved. If the acetic acid has been present for any length of time, however, the plates will have been ruined beyond repair, the lead parts being dissolved by the acid.
If the electrolyte of a battery on charge has a white, milky look, there may be impurities which cause numerous minute bubbles to form, such bubbles giving the electrolyte its milky appearance. The milky appearance may be due to the use of "hard" water in refilling, this water containing lime.
The electrolyte as seen with the acid of an electric lamp or flashlight should be perfectly clear and colorless. Any scum, particles of dirt, any color whatsoever shows that the electrolyte is impure. This calls for dumping out the electrolyte, filling and rinsing with pure water, refilling with new electrolyte and putting the battery back on the charging line. Of course, this may not cause the battery to charge satisfactorily, which may be due to the troubles already described.
Should it ever happen that it is impossible to send a current through a charging circuit go over all the connections to make sure that you have good contact at each battery terminal, and that there are no loose inter-cell connectors. If all connections to the batteries are good, and there are no loose inter-cell connectors, cut out one battery at a time until you start the current flowing, when you cut out some particular battery. This battery should then be opened without further tests, as it is without a doubt in a bad condition.
The conditions which may exist when a battery will not charge, as shown especially by cadmium tests, are as follows:
(a) The battery may have been allowed to remain in a discharged condition, or the owner may have neglected to add water, with the result that the electrolyte did not cover the plates. In either case a considerable amount of crystallized sulphate will have formed in the plates. Plates in such a condition will require a charge of about a week at a low rate and will then have to be discharged and recharged again. Several such cycles of charge and discharge may be necessary. It may even be impossible to charge such a battery, no matter how many cycles of charge and discharge are given. If the owner admits that his battery has been neglected and allowed to stand idle for a considerable time, get his permission to open the battery.
(b) The battery may have been overheated by an excessive charging rate, or by putting it on a car in a sulphated condition. The normal charging rate of the generator on the car will over heat a sulphated battery. Overheated plates buckle their lower edges cut through the separators, causing a short-circuit between plates.
(c) The pockets in the bottoms of the jars may have become filled with sediment, and the sediment may be short-circuiting the plates.
(d) Impurities may have attacked the plates and changed the active materials to other substances which do not form a battery. Such plates may be so badly damaged that they are brittle and crumbled. Acetic acid from improperly treated separators will dissolve lead very quickly, and may even cause an open circuit in the cell.
(e) The conditions described in (a), (b), and (c) will permit a charging current to pass through the battery, but the plates will not become charged. It is possible, of course, but not probable, that a condition may exist in which all the plates of one or both groups of a cell may be broken from the connecting straps, or inter-cell connectors may be making no contact with the posts. In such a case, it would be impossible to send a charging current through the battery. Acetic acid from improperly treated separators, and organic matter introduced by the use of impure water in refilling will attack the lead of the plates, especially at the upper surface of the electrolyte, and may dissolve all the plate lugs from the connecting straps and cause an open-circuit.