1. Plates 2. Separators 3. Jars in which Plates, Separators, and Electrolyte are placed 4. Wooden case 5. Cell Connectors, and Terminals 6. Electrolyte
Most battery diseases are contagious, and if one part fails, some of the other parts are Affected. These diseases may best be considered in the order in which the parts are given in the foregoing list.
PLATE TROUBLES
Plates are the "vitals" of a battery, and their troubles affect the life of the battery more seriously than those of the other parts. It is often difficult to diagnose their troubles, and the following descriptions are given to aid in the diagnosis.
1. Over discharge. Some battery men say that a battery is suflphated whenever anything is wrong with it. Sulphation is the formation of lead sulphate on the plates. As a battery of the lead acid type discharges, lead sulphate must form. There can be no discharge of such a battery without the formation of lead sulphate, which is the natural product of the chemical reactions by virtue of which current may be drawn from the battery. This sulphate gradually replaces the lead peroxide of the positive plate, and the spongy lead of the negative plate. When a battery has been discharged until the voltage per cell has fallen to the voltage limits, considerable portions of the lead peroxide and spongy lead remain on the plates. The sulphate which is then present is in a finely divided, porous condition, and can readily be changed back to lead peroxide and spongy lead by charging the battery.
If the discharge is continued after the voltage has fallen to the voltage limits, an excessive amount of sulphate forms. It fills up the pores in the active materials, and covers up much of the active material which remains, so that it is difficult to change the sulphate back to active material. Moreover, the expansion of active material which takes place as the sulphate forms is then so great that it causes the active material to break off from the plate and drop to the bottom of the jar.
2. Allowing a Battery to Stand Idle. When lead sulphate is first formed, it is in a finely divided, porous condition, and the electrolyte soaks through it readily. If a battery which has been discharged is allowed to stand idle without being charged, the lead sulphate crystals grow by the combination of the crystals to form larger crystals. The sulphate, instead of having a very large surface area, upon which the electrolyte may act in changing the sulphate to active material, as it does when it is first formed, now presents only a very small surface to the electrolyte, and it is therefore only with great difficulty that the large crystals of sulphate are changed to active material. The sulphate is a poor conductor, and furthermore, it covers up much of the remaining active material so that the electrolyte cannot reach it.
A charged battery will also become sulphated if allowed to stand idle, because it gradually becomes discharged, even though no wires of any kind are attached to the battery terminals. How this takes place is explained later. The discharge and formation of sulphate continue until the battery is completely discharged. The sulphate then gradually forms larger crystals as explained in the preceding paragraph, until all of the active material is either changed to sulphate, or is covered over by the sulphate so that the electrolyte cannot reach it. The sulphate thus forms a high resistance coating which hinders the passage of charging current through the battery and causes heating on charge. It is for this reason that sulphated plates should be charged at a low rate. The chemical actions which are necessary to change the sulphate to active material can take place but very slowly, and thus only a small current can be absorbed. Forcing a large current through a sulphated battery causes heating since the sulphate does not form uniformly throughout the plate, and the parts which are the least sulphated will carry the charging current, causing them to become heated. The heating damages the plates and separators, and causes buckling, as explained later.
If batteries which have been discharged to the voltage limits are allowed to stand idle without being charged, they will, of course, continue to discharge themselves just as fully charged batteries do when allowed to stand idle.