This condition is found in batteries that have been charged with the acid below the tops of the plates. The part of the plate above the acid is continually being heated by the charging current. It becomes hard and shiny, and has cracks running through it. The peroxide becomes orange or brick colored, and the grid deteriorates. The part of the plate below the electrolyte suffers also, as explained more fully on page 71. Such plates should be discarded if any considerable portion of the plates is affected. Plates in which 1/2 to 1 inch of the upper parts are affected may be used again if otherwise in good condition.
Plates Which Have Been Charged in Wrong Direction
Such plates have been partly reversed, so that there is lead peroxide and spongy lead on both positive and negative plates, and such plates are generally worthless. If the active materials have not become loosened from the grids, and the grids have not been disintegrated and broken, the plates may sometimes be reversed by a long charge at a low rate in the right direction. If this does not restore the plates, discard them.
SEPARATOR TROUBLES
Separators form the weakest part of a battery, but at the same time perform a very important duty. New separators should therefore be installed whenever a battery is opened for repairs. Repairs should never be attempted on separators.
1. Not Properly Expanded Before Installation. Separators in stock must be kept moist. This not only prevents them from becoming dry and brittle, but keeps them fully expanded. If separators which have been kept dry in stock are installed in a battery, they do their expanding inside the battery. This causes them to project beyond the edges of the plates. The crowding to which they are subjected causes them to crack. Cracked separators permit "treeing" between plates, with a consequent short circuit.
2. Not Properly Treated. Separators which have not been given the proper chemical treatment are likely to develop Acetic acid after they are in the battery. Acetic acid dissolves the lead grids, the plate lugs, and the plate connecting straps rapidly. If the plate lugs are found broken, and crumble easily, acetic acid is very likely present, especially if an odor like that of vinegar is noticeable. Improperly treated separators will cause a battery to show low voltage at high rates of discharge, particularly in cold weather, and will also cause the negatives to give poor cadmium readings, which may lead the repairman to conclude that the negatives are defective. The separators of batteries which have been shipped completely assembled without electrolyte and with moistened plates and separators will sometimes have the same effect.
3. Cracked. Separators should be carefully "candled" — placed in front of a light and looked through. Cracks, resinous streaks, etc., mean that the separator should not be used, as it will breed trouble.
4. Rotted and Carbonized. This may be the result of old age, overheating, or high gravity electrolyte.
5. Pores Clogged. Impurities, dirt from impure water, and lead sulphate fill the pores of a separator and prevent the proper circulation of the electrolyte. The active material of frozen positives also fills up the pores of a separator.