SYNTHETIC STONES
For over 200 years mineralogists have been devising techniques for producing synthetic minerals in the laboratory, and attempts have been made, sometimes with considerable success, to apply these techniques to the production of synthetic gemstones. To qualify as a synthetic gemstone the man-made product must be identical chemically and structurally with its natural counterpart. Sapphire, ruby, spinel, emerald, and rutile in gem quality have been brought to commercial production.
Two of the basic techniques used in producing synthetic gems are the flame-fusion and the hydrothermal processes.
The Verneuil furnace, for making synthetic gem rough. A mixture of hydrogen (H) and oxygen (O) burns almost explosively, heating the fusion chamber (F) to high temperatures. For example, powdered aluminum oxide and coloring agents are sifted down from hopper (A) to the fusion chamber and form a cylindrical boule (B) on an adjustable stand (C).
In the flame-fusion process—invented in 1904 by the French chemist Verneuil—powdered aluminum oxide, containing coloring agents, is sieved down through the flame of a vertical blowtorch furnace. As it passes through the flame, the powder melts and accumulates as drops on an adjustable stand just below the flame, where it forms a single crystal boule of the synthetic rough. In a few hours a boule of several hundred carats can be formed. When such furnaces are operated in banks of several hundred units, the commercial production of corundum alone becomes possible at the rate of many tons a year. Through the years, of course, refinements have been made on Verneuil’s original furnace.
In the hydrothermal process, which differs greatly from Verneuil’s flame-fusion process, crystals are grown from solutions of the raw materials that have been subjected to varying conditions of very high pressure and temperature. Some of the quartz used for electronics purposes also is manufactured in this way.
Since chemical composition and crystal structure are the basic characteristics by which a gemstone is identified, and these characteristics are identical in both the manufactured stone and its natural counterpart, the synthetic gemstones offer a very serious challenge to those concerned with gem identification.
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GEM LORE
All sorts of magic and symbolic properties have been ascribed to gemstones through the ages; for example, the cat’s-eye has been prescribed as a cure for paleness, citrine has been worn as a protection from danger, and the opal cherished as the symbol of hope. The result has been the creation of an intricate, chaotic, and contradictory but interesting mass of gem lore.