- 1. Cinnamon oil,
- 2. Clove oil,
- 3. Cardamom oil,
- 4. Coriander oil,
- 5. Nutmeg oil (ethereal),
- 6. Mace oil (ethereal).
The amount of ether oil that should be used in place of the corresponding spice is a matter of taste. The maximum percentage of the oil in the respective spice might serve as a standard, as for example in the case of cinnamon oil, which is contained in the bark to the extent of 1 percent, about the hundredth part of the oil would be required to correspond with the prescribed weight of the bark. But as the yield of oil from one and the same kind of spice varies to a considerable extent according to season and locality, the percentage value can only be used as a general guide, and the final decision must be always regulated by the taste.
The ethereal oils can be incorporated in the cacao preparations (mass, powder etc.) either in a spirit solution or ground down with sugar. The latter method is naturally only used when sugar is to be added to cacao preparations. To prepare the alcoholic solution 10 parts of the ethereal oil are dissolved in 90 parts of strong alcohol. The mixture of oil with sugar can be made by triturating 2·5 parts of the ethereal oil with 100 parts of sugar in a porcelain mortar and grinding down with the pestle until the sugar and oil are intimately mixed. Of the alcoholic solution it is necessary to take 10 parts, and of the oil-sugar 40 parts to one part of ethereal oil.
II. Peru balsam and Gum benzoin.
Peru balsam is at present very much used as a perfume in chocolate making. It is obtained from the Papilionaceous Myroxylon Pereira which is indigenous to the western part of Central America. It is a thick, brownish black, liquid balsam which in thin layers appears transparent and has a peculiar smell and burning taste; it is almost completely soluble in alcohol, chloroform, and acetic ether. The aromatic substance of this balsam is cinnameïn, which consists essentially of the esters of benzoic and cinnamic acids and benzyl alcohol together with an alcoholic body “Peruviol”, which has the smell of honey. In addition to cinnameïn (71-77 per cent) the balsam also contains a resin ester (13-17 percent). According to K. Dieterich, Peru balsam is the better for containing more cinnameïn and less resin ester. Peru balsam is adulterated with fatty oils, copaiva, gurjun-balsam, storax, colophony, turpentine, and tolu balsam. In regard to the chemical investigation of this balsam the work of K. Dieterich[159] may be consulted.
The Sumatra benzoin is the most important of the commercial kinds for chocolate making. It is obtained from one of the Styracae, Styrax benzoin, and is a reddish grey mass in which separate tiers of resin are embedded. Benzoic acid and vanillin are the most important constituents. It is adulterated with Palembang benzoin, colophony, dammer, storax, and turpentine. Respecting the chemical investigation of commercial benzoin the above-mentioned work of K. Dieterich may also be referred to.
Benzoin is almost exclusively used for the preparation of chocolate varnish and sweets laquer, which are prepared by dissolving from 25 to 45 grammes of the laquer body in 100 grammes of strong spirit. The laquer body may contain varying quantities of benzoin and bleached shellac. The decorations of chocolate are painted with this laquer in order to give them a glistening appearance and greater durability.
V. Colouring materials.
The following colouring materials are permitted by the German law of the 14th May 1879 to be used for sugar goods and consequently also for chocolate and cacao preparations.
- White: finest flour starch.
- Yellow: saffron, safflower, turmeric.
- Blue: litmus, indigo solution.
- Green: spinach juice as well as mixtures of the permitted blue and yellow colours.>
- Red: carmine, cochineal, madder red.
- Violet: mixtures of the harmless blue and red colours.
- Brown: burnt sugar, licorice juice.
- Black: chinese ink.