Acids have likewise a great affinity with the Phlogiston. When we come to treat of each Acid in particular, we shall examine the combinations of each with the Phlogiston: they differ so widely from one another, and many of them are so little known, that we cannot at present give any general idea of them.
SECTION II.
Of Alkalis.
Alkalis are Saline combinations, in which there is a greater proportion of earth than in Acids. The principal arguments that may be adduced to prove this fact are these: First; if they be treated in the manner proposed above for analyzing Saline Substances, we obtain from them a much greater quantity of earth than we do from Acids. Secondly; by combining certain Acids with certain earths we can produce Alkalis; or at least such saline compounds as greatly resemble them. Our third and last argument is drawn from the properties of those Alkalis which, when pure and unadulterated with any other principle, have less affinity with water than Acids have, and are also more fixed, resisting the utmost force of fire. On this account it is that they have obtained the title of Fixed, as well as to distinguish them from another species of Alkali, to be considered hereafter, which is impure and volatile.
Though fixed Alkalis, when dry, sustain the utmost violence of fire without flying off in vapours, it is remarkable that, being boiled with water in an open vessel, considerable quantities of them rise with the steam: an effect which must be attributed to the great affinity between these two substances, by means whereof water communicates some part of its volatility to the fixed salt.
Alkalis freed of their superfluous humidity by calcination attract the moisture of the air, but not so strongly as Acids: so that it is easier to procure and preserve them in a solid form.
They flow in the fire, and are then capable of uniting with vitrifiable earths, and of forming therewith true glass, which, however, will partake of their properties, if they be used in sufficient quantity.
As they melt more readily than vitrifiable earth, they facilitate its fusion; so that a weaker fire will reduce it to glass, when a fixed Alkali is joined with it, than will melt it without that addition.
Alkalis are known by their taste, which is acrid and fiery; and by the properties they possess of turning vegetable blues and violet colours green; particularly syrop of violets.