It may be separated from the sulphur with which is combined, by only exposing it to the fire, without any additament; for the sulphur is either consumed or sublimed, and leaves the Bismuth behind.
SECTION III.
Of Zinc.
Zinc to appearance differs but little from Bismuth, and has even been confounded with it by several authors. Nevertheless, besides that it has something of a blueish cast, and is harder than Bismuth, it differs from it essentially in its properties, as will presently be shewn. These two metallic substances scarce resemble each other in any thing, but the qualities common to all semi-metals.
Zinc melts the moment it grows red in the fire, and then also begins to turn to a calx, which, like any other metallic calx, may be reduced by means of the phlogiston: but if the fire be considerably increased, it sublimes, flames, and burns like an oily matter; which is a proof of the great quantity of phlogiston in its composition. At the same time abundance of flowers rise from it in the form of white flakes, flying about in the air like very light bodies; and into this form may the whole substance of the Zinc be converted. Several names have been given to these flowers, such as Pompholyx, Philosophic Wool. They are supposed to be no other than the Zinc itself deprived of its phlogiston; yet no body has hitherto been able to resuscitate them in the form of Zinc, by restoring their phlogiston according to the methods used in the reduction of metals. Though they rise in the air with very great ease while the Zinc is calcining, yet when once formed they are very fixed; for they withstand the utmost violence of fire, and are capable of being vitrified, especially if joined with a fixed alkali. They are soluble in acids.
Zinc unites with all metalline substances, except Bismuth. It has this singular property, that being mixed with Copper, even in a considerable quantity, such as a fourth part, it does not greatly lessen the ductility thereof, and at the same time communicates to it a very beautiful colour not unlike that of Gold: on which account the composition is frequently made, and produces what is called Brass. This metal melts much more easily than Copper alone, because of the Zinc with which it is alloyed. If it be exposed to a great degree of heat, the Zinc which it contains takes fire, and sublimes in white flowers, just as when it is pure.
It is to be observed, that Brass is ductile only while it is cold, and not then, unless the Zinc used in making it was very pure; otherwise the composition will prove but a Tombac or Prince's Metal, having very little malleability.
Zinc is very volatile, and carries off with it any metallic substance with which it is fused, making a kind of sublimate thereof. In the furnaces where they smelt ores containing Zinc, the matter thus sublimed is called Cadmia Fornacum, to distinguish it from the native Cadmia called also Calamine, or Lapis Calaminaris; which, properly speaking, is an ore of Zinc, containing a great deal of that semi-metal, together with some Iron, and a stony substance. The name of Cadmia Fornacum is not appropriated solely to the metallic sublimates procured by means of Zinc, but is given in general to all the metallic sublimates found in smelting houses.
If a violent and sudden heat be applied to Zinc, it sublimes in its metalline form; there not being time for it to burn and be resolved into flowers.
This semi-metal is soluble in all the acids, but especially in spirit of nitre, which attacks and dissolves it with very great violence.