Of Vinegar.
If wine, which has gone through this second stage of fermentation, be distilled, instead of an ardent spirit, only an acid liquor is obtained, which is called Distilled Vinegar.
This acid has the same properties as the mineral acids of which we have already treated; that is, it unites with alkaline salts, absorbent earths, and metallic substances, and therewith forms neutral saline combinations.
Its affinity with these substances observes the same order as that observed by the mineral acids with regard to the same substances; but in general it is weaker; that is, any mineral acid is capable of expelling the acid of Vinegar out of all matters with which it is united.
Vinegar hath likewise a greater affinity than sulphur with alkalis: whence it follows, that it is capable of decompounding that combination of sulphur with an alkali called Liver of Sulphur, and of precipitating the sulphur it contains.
The acid of Vinegar is always clogged with a certain proportion of oily parts, which greatly weaken it, and deprive it of much of its activity; and for this reason it is not near so strong as the mineral acids, which are not entangled with any oil. By distillation, indeed, it may be freed from this oil, and at the same time from the great quantity of water which in a manner suffocates it, and by that means may be brought much nearer to the nature of the mineral acids: but this attempt hath not yet been prosecuted with the assiduity it deserves. Besides distillation, there is another way of freeing Vinegar from a good deal of its phlegm; and that is, by exposing it to a hard frost, which readily congeals the watery part into ice, while the acid retains its fluidity.
Vinegar, saturated with a fixed alkali, forms a neutral oily salt, of a dark colour, which is semi-volatile, melts with a very gentle heat, flames when thrown upon burning coals, and dissolves in spirit of wine, of which, however, it requires six parts to complete the solution. This solution being evaporated to dryness leaves a matter in the form of leaves lying on each other; on which account it hath obtained the name of Terra Foliata. The same foliated matter will be obtained, though the salt be not previously dissolved in spirit of wine; but not so readily. This salt is also called Regenerated Tartar. Under the head of Tartar we shall see the reason of these different appellations. Regenerated Tartar is also in some degree capable of crystallizing: for this purpose a solution thereof in water must be slowly evaporated to the consistence of a syrup, and then suffered to stand quiet in a cool place; by which means it will shoot into clusters of crystals, lying one upon another, not unlike the feathers on a quill.
With Vinegar and several absorbent earths, such as calcined pearls, coral, shells of fish, &c. are also formed neutral saline compounds, each of which takes the name of the particular earth employed in its composition.
Vinegar perfectly dissolves Lead, and converts it to a neutral metallic salt, which shoots into crystals, and has a sweet saccharine taste. This compound is called Sugar of Lead, or Sal Saturni.
If Lead be exposed to the bare vapour of Vinegar, it will be thereby corroded, calcined, and converted into a white matter much used in painting, and known by the name of Ceruse; or, when it is finer than ordinary, White Lead.