"I haven't tested this sample for nitrogen yet, but there's got to be some, because ammonia is NH3. Obviously, there's a vein of solid nitrogen down under the Hill. As the heat from the pile room penetrated downward, this slowly warmed up. Some of it turned gaseous, generating terrific pressure; and finally that pressure forced the gas up into the pile room.
"Now, when you have a nitrogen-hydrogen mixture at 500 degrees and 600 atmospheres, in the presence of a suitable catalyst, you get about a 45 percent yield of ammonia—"
"You looked that up," said Catherine accusingly.
He chuckled. "My dear girl," he said, "there are two ways to know a thing: you can know it, or you can know where to look it up. I prefer the latter." After a moment: "Naturally, this combination decreases the total volume of gas; so the pump has to pull in more hydrogen from outside to satisfy its barystat, and more nitrogen is welling from below all the time. We've been operating quite an efficient little ammonia factory down there, though it should reach equilibrium as to pressure and yield pretty soon.
"The Haber process catalyst, incidentally, is spongy iron with certain promoters—potassium and aluminum oxides are excellent ones. In other words, it so happened that the Hill is a natural Haber catalyst, which is why we've had this trouble."
"And I suppose the reaction is endothermic and absorbs heat?" asked Catherine.
"No ... as a matter of fact, it's exothermic, which is why the pile is actually a little hotter than usual, and that in spite of having to warm up all that outside air. But ammonia does have a considerably higher specific heat than hydrogen. So, while the gas in our pipes has the same caloric content, it has a lower temperature."
"Ummm—" Vesey rubbed his chin. "And the radiation?"
"Nitrogen plus neutrons gives carbon-14, a beta emitter."
"All right," said Catherine. "Now tell us how to repair the situation."