“Those who are interested in the preparation of coak would do well to remember that every 96 ounces of coal would furnish four ounces at the least of oil, probably six ounces might be obtained; but if we put the product so low as five ounces from 100, and suppose a coak oven to work off only 100 tons of coal in a year, there would be a saving of five tons of oil, which would yield above four tons of tar; the requisite alteration in the structure of the coak ovens, so as to make them a kind of distilling vessels, might be made at a very trifling expense.”—5th ed., 1789, vol. ii. p. 351.
We have yet to chronicle another chapter in the history of coal philosophy before finishing with this part of the subject. There is a branch of manufacture carried on, especially in Scotland, which results in the production of burning and lubricating oils, and solid paraffin, a wax-like substance which is used for candle-making. The manufacture of candles out of coal will perhaps be a new revelation to many readers of this book. It must be admitted, however, that the term “coal” is here being extended to only partially fossilized vegetation of younger geological age than true coal, and to bituminous shales of various ages. Shale, geologically considered, is hardened mud; it may be looked upon as clay altered by time and pressure. Now if the mud, at the period of its deposition, was much mixed up with vegetable matter, we should have in course of time a mixture of more or less carbonized woody fibre with mineral matter, and this would be called a carbonaceous or bituminous shale. Shales of this kind often contain as much as 80 to 90 per cent. of mineral matter, and seldom more than 20 per cent. of volatile matter, i.e. the portion lost on ignition, and consisting chiefly of the carbonaceous constituents.
The story of the shale-oil industry is soon told. About the year 1847 oil was “struck” in a coal mine at Alfreton in Derbyshire, and in the hands of Mr. James Young this supply furnished the market with burning-oil for nearly three years. Then the spring became exhausted, and Mr. Young and his associates had to look out for another source of oil. Be it remembered that this happened some nine years before the utilization of the great American petroleum deposits. Many kinds of vegetable matter were submitted to destructive distillation before a substance was found which could be profitably worked, but at length Mr. Young tried a kind of cannel coal which had about that time been introduced for gas making. This substance was called Boghead gas coal or Torbane Hill mineral, from the place where it occurred, which is at Bathgate in Linlithgow. This mineral was found to yield a large amount of paraffin oil and solid paraffin on destructive distillation, and from that time (1850) to this, the industry has been carried on at Bathgate and other parts of Scotland, where similar carbonaceous deposits occur.
It may seem a matter of unimportance at the present time whether this Torbane Hill mineral is a true coal or not. About forty years ago, however, the decision of this question involved a costly law-suit in Edinburgh. The proprietor of the estate had granted a lease to a firm, conveying to the latter the right to work coal, limestone, ironstone, and certain other minerals found thereon, but excluding copper and all other minerals not mentioned in the contract. The lessees then found that this particular carbonaceous mineral was of very great value, both on account of the high quality of the gas, and afterwards on account of the paraffin which it furnished by Young’s process of distillation. Thereupon the lessor brought an action against the lessees, claiming £10,000 damages, on the ground that the latter had broken the contract by removing a mineral which was not coal. Experts gave evidence on both sides; some declared in favour of the substance being coal, others said it was a bituminous shale, while others called it bituminated clay, or refused to give it a name at all. Judgment was finally given for the defendants, so that in the eye of the law the mineral was considered a true coal. As a matter of fact, it is impossible to draw a hard and fast line between coal and bituminous shale, as the one is connected with the other by a series of intermediate minerals, and the Torbane Hill mineral happens to form one of the links. It contains about 69 per cent. of volatile matter, and leaves 31 per cent. of residue, consisting of 12 parts of carbon and 19 of ash.
The manufacture started by Young has developed into an important industry, in spite of the fact that the original Torbane Hill coal has become exhausted, and that enormous natural deposits of petroleum are worked in America, Russia, and elsewhere. There are now some fifteen companies at work in Scotland, representing an aggregate capital of about two and a half million pounds sterling. Bituminous shales of different kinds are distilled at a low red heat in iron retorts, and from the volatile portions there are separated those valuable products which have already been alluded to, viz. burning and lubricating oils, solvent mineral oil, paraffin wax for candles, and ammonia. We may fairly claim these as coal products, although the shales used contain much mineral matter, the carbon averaging about 20 per cent., the hydrogen three per cent., the nitrogen 0·7, and the ash about 67 per cent. The shales worked are approximately of the same age as true coal, i.e. Carboniferous. The Scotch companies are distilling about two million tons of shale per annum, this quantity producing about sixty million gallons of crude oil, and giving employment to over 10,000 hands.
It is not the province of the present work to enter into the chemical nature of the products of destructive distillation in any greater detail than is necessary to enable the general reader to know something of the recent discoveries in the utilization of these products. We shall, however, have occasion later on to make ourselves acquainted with the names of some of the more important raw materials which are derived from this source, and certain preliminary explanations are indispensable. In the first place then, let us start from the fact that coal—including carbonaceous shale and lignite—when heated in a closed vessel gives gas, tar, coke, and a watery liquor. A clear understanding must be arrived at concerning the manner in which these products arise.
There is a widely-spread notion that the substances derived from coal and utilized for industrial purposes are present in the mineral itself, and that the art of the chemist has been exercised in separating the said substances by various processes. This idea must be at once dispelled. It is true that there is a small quantity of water and a certain amount of gas already present in most coals, but these are quite insignificant as compared with the total yield of gas and watery liquor. So also with respect to the tar; it is possible that in some highly bituminous minerals we might dissolve out a small quantity of tarry matter by the use of appropriate solvents, but in the coals mostly used for gas-making not a trace of tar exists ready formed, and still less can it be said that the coal contains coke. All these products are formed by the chemical decomposition of the coal under the influence of heat, and their nature and quantity can be made to vary within certain limits by modifying the temperature of distillation.
Having once realized this principle with respect to coal itself, it is easy to extend it to the products of its destructive distillation. The tar, for instance, is a complicated mixture of various substances, among which hydrocarbons—i.e. compounds of carbon with hydrogen—largely predominate. The different components of coal-tar can be separated by processes which we shall have to consider subsequently. Of the compounds thus isolated some few are immediately applicable for industrial purposes, but the majority only form the raw materials for the manufacture of other products, such as colouring-matters and medicines. Now these colouring-matters and other finished products no more exist in the tar than the latter exists in the coal. They are produced from the hydrocarbons, &c., present in the tar by chemical processes, and bear much about the same relationship to their parent substances that a steam-engine bears to the iron ore out of which its metallic parts are primarily constructed. Just as the mechanical skill of the engineer enables him to construct an engine out of the raw material iron, which is extracted from its ore, and converted into steel by chemical processes, so the skill of the chemist enables him to build up complex colouring-matters, &c., out of the raw materials furnished by tar, which is obtained from coal by chemical decomposition.
The illuminating gas which is obtained from coal by destructive distillation consists chiefly of hydrogen and gaseous hydrocarbons, the most abundant of the latter being marsh gas. There are also present in smaller quantities the two oxides of carbon, the monoxide and the dioxide, which are gaseous at ordinary temperatures, together with other impurities. Coal-gas is burnt just as it is delivered from the mains—it is not at present utilized as a source of raw material in the sense that the tar is thus made use of. In some cases gas is used as fuel, as in gas-stoves and gas-engines, and in the so-called “gas-producers,” in which the coal, instead of being used as a direct source of heat, is partially burnt in suitable furnaces, and the combustible gas thus arising, consisting chiefly of carbon monoxide, is conveyed to the place where it undergoes complete combustion, and is thus utilized as a source of heat.
Summing up the uses of coal thus far considered, we see that this mineral is being consumed as fuel, for the production of coke, for the manufacture of gas, and in many other ways. Lavishly as Nature has provided us with this source of power and wealth, the idea naturally suggests itself whether we are not drawing too liberally upon our capital. The question of coal supply crops up from time to time, and the public mind is periodically agitated about the prospects of its continuance. How long we have been draining our coal resources it is difficult to ascertain. There is some evidence that coal-mining was carried on during the Roman occupation. In the reign of Richard I. there is distinct evidence of coal having been dug in the diocese of Durham. The oldest charters take us back to the early part of the thirteenth century for Scotland, and to the year 1239 for England, when King Henry III. granted a right of sale to the townsmen of Newcastle. With respect to the metropolis, Bishop Watson, on the authority of Anderson’s History of Commerce, states that coal was introduced as fuel at the beginning of the fourteenth century. In these early days, when it was brought from the north by ships, it was known as “sea-coal”:—