OZONE.
The singular gas termed ozone has attracted a large amount of attention from chemists and meteorologists. The vague ideas which were formed as to its nature when as yet it had been but newly discovered, have given place gradually to more definite views; and though we cannot be said to have thoroughly mastered all the difficulties which this strange element presents, yet we know already much that is interesting and instructive.
Let us briefly consider the history of ozone.
Nine years after Priestley had discovered oxygen, Van Marum, the electrician, noticed that when electric sparks are taken through that gas, a peculiar odour is evolved. Most people know this odour, since it is always to be recognized in the neighbourhood of an electrical machine in action. In reality, it indicates the presence of ozone in the air. But for more than half a century after Van Marum had noticed it, it was supposed to be the “smell of electricity.”
In 1840, Schönbein began to inquire into the cause of this peculiar odour. He presently found that it is due to some change in the oxygen; and that it can be produced in many ways. Of these, the simplest, and, in some respects, the most interesting, is the following:—“Take sticks of common phosphorus, scrape them until they have a metallic lustre, place them in this condition under a large bell-jar, and half-cover them with water. The air in the bell-jar is soon charged with ozone, and a large room can readily be supplied with ozonized air by this process.”
Schönbein set himself to inquire into the properties of this new gas, and very interesting results rewarded his researches. It became quite clear, to begin with, that whatever ozone may be, its properties are perfectly distinct from those of oxygen. Its power of oxidizing or rusting metals, for example, is much greater than that which oxygen possesses. Many metals which oxygen will not oxidize at all, even when they are at a high temperature, submit at once to the influence of ozone. But the power of ozone on other substances than metals is equally remarkable. Dr. Richardson states that, when air is so ozonized as to be only respirable for a short time, its destructive power is such that gutta-percha and india-rubber tubings are destroyed by merely conveying it.
The bleaching and disinfecting powers of ozone are very striking. Schönbein was at first led to associate them with the qualities of chlorine gas; but he soon found that they are perfectly distinct.
It had not yet been shown whether ozone was a simple or a compound gas. If simple, of course it could be but another form of oxygen. At first, however, the chances seemed against this view; and there were not wanting skilful chemists who asserted that ozone was a compound of the oxygen of the air with the hydrogen which forms an element of the aqueous vapour nearly always present in the atmosphere.