In considering this question, Poincaré’s own remark—“Maxwell does not give a mechanical explanation of electricity and magnetism, he is only concerned to show that such an explanation is possible”—is most important.
We cannot find in the “Electricity” an answer to the question—What is an electric charge? Maxwell did not pretend to know, and the attempt to give too great definiteness to his views on this point is apt to lead to a misconception of what those views were.
On the old theories of action at a distance and of electric and magnetic fluids attracting according to known laws, it was easy to be mechanical. It was only necessary to investigate the manner in which such fluids could distribute themselves so as to be in equilibrium, and to calculate the forces arising from the distribution. The problem of assigning such a mechanical structure to the ether as will permit of its exerting the action which occurs in an electro-magnetic field is a harder one to solve, and till it is solved the question—What is an electric charge?—must remain unanswered. Still, in order to grasp Maxwell’s theory this knowledge is not necessary.
The properties of ether in dielectrics and in conductors must be quite different. In a dielectric the ether has the power of storing energy by some change in its configuration or its structure; in a conductor this power is absent, owing probably to the action of the matter of which the conductor is composed.
When we are said to charge an insulated conductor we really act on the ether in the neighbourhood of the body so as to store it with energy; if there be another conductor in the field we cannot store energy in the ether it contains. As, then, we pass from the outside of this conductor to its interior there is a sudden change in some mechanical quantity connected with the ether, and this change shows itself as a force of attraction between the two conductors. Maxwell called the change in structure, or in property, which occurs when a dielectric is thus stored with electrostatic energy, Electric Displacement; if we denote it by D, then the electric force R is equal to 4πD/K, and hence the energy in a unit of volume is 2πD²/K, where K is a quantity depending on the insulator.
Now, D, the electric displacement, is a quantity which has direction as well as magnitude. Its value, therefore, at any point can be represented by a straight line in the usual way; inside a conductor it is zero. The total change in D, which takes place all over the surface of a conductor as we enter it from the outside measures, according to Maxwell, the total charge on the conductor. At points at which the lines representing D enter the conductor the charge is negative; at points at which they leave it the charge is positive; along the lines of the displacement there exists throughout the ether a tension measured by 2πD²/K; at right angles to these lines there is a pressure of the same amount.
In addition to the above the components of the displacement D must satisfy certain relations which can only be expressed in mathematical form, the physical meaning of which it is difficult to state in non-mathematical language.
When these relations are so expressed the problem of finding the value of the displacement at all points of space becomes determinate, and the forces acting on the conductors can be obtained. Moreover, the total change of displacement on entering or leaving a conductor can be calculated, and this gives the quantity which is known as the total electrical charge on the conductor. The forces obtained by the above method are exactly the same as those which would exist if we supposed each conductor to be charged in the ordinary sense with the quantities just found, and to attract or repel according to the ordinary laws.
If, then, we define electric displacement as that change which takes place in a dielectric when it becomes the seat of electrostatic energy, and if, further, we suppose that the change, whatever it be mechanically, satisfies certain well-known laws, and that in consequence certain pressures and tensions exist in the dielectric, electrostatic problems can be solved without reference to a charge of electricity residing on the conductors.
Something such as this, it appears to me, is Maxwell’s theory of electricity as applied to electrostatics. It is not necessary, in order to understand it, to know what change in the ether constitutes electric displacement, or what is an electric charge, though, of course, such knowledge would render our views more definite, and would make the theory a mechanical one.