The “effects” provided by Volta’s pile and crown-of-cups are therefore electroscope deflection, sparks, and shocks. Later in the letter, he describes the stimulation of sight, taste, and hearing as noted earlier, but nowhere does he mention chemical phenomena of any kind, or the heating of a wire joining the terminals of either device. Hence, except for the additional physiological responses, he adds nothing to the catalog of observations on which instruments might be based. His familiarity with the moods of the torpedo (electric eel) seems to be intimate.
The reading of Volta’s letter to the Royal Society on June 26, 1800, its publication in the Society’s Philosophical Transactions (in French) immediately thereafter, and its publication in English in the Philosophical Magazine for September 1800,[5] gave scientists throughout Europe an easily constructed and continuously operating electric generator with which innumerable new physical, chemical, and physiological experiments could be made. Editor-engineer William Nicholson read Volta’s letter before its publication and, by the end of April, he and surgeon Anthony Carlisle had built a voltaic pile. Applying a drop of water to improve the “connection” of a wire lying on a metal plate, they happened to notice gas bubbles forming on the wire, and pursued the observation to the point of identifying the electrical decomposition of water into hydrogen and oxygen.
Within two or three years innumerable electrochemical reactions had been described, some of which, one might think, could have served as operating principles for electrical instruments. Although the phenomena of gas formation and metal deposition were in fact widely used as crude indicators of the polarity and relative strength of voltaic piles and chemical cells during the period 1800-1820 (and the gas bubbles were made the basis of a telegraph receiver by S. T. Soemmering), the quantitative laws of electrolysis were not worked out by Faraday until after 1830, and not until 1834 was he satisfied that the electrolytic decomposition of water was sufficiently well understood to be made the basis for a useful measuring instrument. Describing his water-electrolysis device in that year, he wrote:
The instrument offers the only actual measurer [italics his] of voltaic electricity which we at present possess. For without being at all affected by variations in time or intensity, or alterations in the current itself, of any kind, or from any cause, or even of intermissions of actions, it takes note with accuracy of the quantity of electricity which has passed through it, and reveals that quantity by inspection; I have therefore named it a VOLTAELECTROMETER.[6]
In passing, Faraday commented that the efforts by Gay-Lussac and Thenard to use chemical decomposition as a “measure of the electricity of the voltaic pile” in 1811 had been premature because the “principles and precautions” involved were not then known. He also noted that the details of metal deposition in electrolysis were still not sufficiently understood to permit its use in an instrument.[7]
The heating of the wires in electric circuits must have been observed so early and so often with both electrostatic and voltaic apparatus, that no one has bothered to claim or trace priorities for this “effect.” The production of incandescence, however, and the even more dramatic combustion or “explosion” of metal-foil strips and fine wires has a good deal of recorded history. Among the first to burn leaf metal with a voltaic pile was J. B. Tromsdorff of Erfurt who noted in 1801 the distinctly different colors of the flames produced by the various common metals. In the succeeding few years, Humphry Davy at the Royal Institution frequently, in his public lectures, showed wires glowing from electric current.
Early electrical instrumentation based on the heating effect took an unusual form. Shortly after 1800, W. H. Wollaston, an English M.D., learned a method for producing malleable platinum. He kept the process secret, and for several years enjoyed an extremely profitable monopoly in the sale of platinum crucibles, wire, and other objects. About 1810, he invented a technique for producing platinum wire as fine as a few millionths of an inch in diameter, that has since been known as “Wollaston wire.” For several years preceding 1820, no other instrument could compare the “strengths” of two voltaic cells better than the test of the respective maximum lengths of this wire that they could heat to fusion. One can sympathize with Cumming’s comment in 1821 about “the difficulty in soldering wires that are barely visible.”[8]
Electrical Instrumentation, 1800-1820
The 20 years following the announcement of the voltaic-pile invention were years of intense experimental activity with this device. Many new chemical elements were discovered, beginnings were made on the electrochemical series of the elements, the electric arc and incandescent platinum wires suggested the possibilities of electric lighting, and various electrochemical observations gave promise of other practical applications such as metal-refining, electroplating, and quantity production of certain gases. Investigators were keenly aware that all of the available means for measuring and comparing the electrical aspects of their experiments (however vaguely these “electrical aspects” may have been conceived), were slow, awkward, imprecise, and unreliable.
The atmosphere was such that prominent scientists everywhere were ready to pounce immediately on any reported discovery of a new electrical “effect,” to explore its potentialities for instrumental purposes. Into this receptive environment came H. C. Oersted’s announcement of the magnetic effects of a voltaic circuit, on July 21, 1820.[9]