Thomson and his pupils found that the conductivity induced in gases by X-rays disappeared when the gas was sucked through glass wool.[11] It was also found to be reduced when the air was drawn through narrow metal tubes. Furthermore, it was removed entirely by passing the stream of conducting gas between plates which were maintained at a sufficiently large potential difference. The first two experiments showed that the conductivity was due to something which could be removed from the gas by filtration, or by diffusion to the walls of a metal tube; the last proved that this something was electrically charged.
When it was found, further, that the electric current obtained from air existing between two plates and traversed by X-rays rose to a maximum as the P.D. between the plates increased, and then reached a value which was thereafter independent of this potential difference; and, further, that this conductivity of the air died out slowly through a period of several seconds when the X-ray no longer acted, it was evident that the qualitative proof was complete that gas conduction must be due to charged particles produced in the air at a definite rate by a constant source of X-rays, and that these charged particles, evidently of both plus and minus signs, disappear by recombination when the rays are removed. The maximum or saturation currents which could be obtained when a given source was ionizing the air between two plates whose potential difference could be varied were obviously due to the fact that when the electric field between the plates became strong enough to sweep all the ions to the plates as fast as they were formed, none of them being lost by diffusion or recombination, the current obtained could, of course, not be increased by further increase in the field strength. Thus gas conduction was definitely shown about 1896 to be electrolytic in nature.
IV. COMPARISON OF THE GASEOUS ION AND THE ELECTROLYTIC ION
But what sort of ions were these that were thus formed? We did not know the absolute value of the charge on a univalent ion in electrolysis, but we did know accurately
. Could this be found for the ions taking part in gas conduction? That this question was answered affirmatively was due to the extraordinary insight and resourcefulness of J. J. Thomson and his pupils at the Cavendish Laboratory in Cambridge, both in working out new theoretical relations and in devising new methods for attacking the new problems of gaseous conduction. These workers found first a method of expressing the quantity
in terms of two measurable constants, called (1) the mobility of gaseous ions and (2) the coefficient of diffusion of these ions. Secondly, they devised new methods of measuring these two constants—constants which had never before been determined. The theory of the relation between these constants and the quantity
will be found in Appendix A. The result is