, the number of molecules in 1 c.c. of gas under standard conditions, were known. But we had only rough guesses as to this number. These guesses varied tenfold, and none of them were based upon considerations of recognized accuracy or even validity.
I. TOWNSEND’S WORK ON
The first attempt at a direct determination of
was published by Townsend in a paper read before the Cambridge Philosophical Society on February 8, 1897.[29] Townsend’s method was one of much novelty and of no little ingenuity. It is also of great interest because it contains all the essential elements of some of the subsequent determinations.
It had been known, even to Laplace and Lavoisier a hundred years before, that the hydrogen gas evolved when a metal dissolves in an acid carries with it an electrical charge. This “natural method” of obtaining a charge on a gas was scarcely studied at all, however, until after the impulse to the study of the electrical properties of gases had been given by the discovery in 1896 that electrical properties can be artificially imparted to gases by X-rays. Townsend’s paper appeared within a year of that time. Enright[30] had indeed found that the hydrogen given off when iron is dissolving in sulphuric acid carries with it a positive charge, but Oliver Lodge[31] had urged that it was not the gas itself which carries the charge but merely the spray, for the frictional electrification of spray was a well-known phenomenon. Indeed, it has always been assumed that the gas molecules which rise from the electrodes in electrolysis are themselves neutral. Townsend, however, first showed that some of these molecules are charged, although there are indeed a million million neutral ones for every one carrying a charge. He found that both the oxygen and the hydrogen which appear at the opposite electrodes when sulphuric acid is electrolyzed are positively charged, while when the electrolyte is caustic potash both the oxygen and the hydrogen given off are negative. Townsend’s electrolyzing currents were from 12 to 14 amperes. He got in this way many more ions per cubic centimeter than he could produce with X-rays, the total charge per cubic centimeter being as large as
When these charged gases were bubbled through water they formed a cloud. This cloud could be completely removed by bubbling through concentrated sulphuric acid or any drying agent, but when the gas came out again into the atmosphere of the room it again condensed moisture and formed a stable cloud. Townsend says that “the process of forming the cloud in positive or negative oxygen by bubbling through water, and removing it again by bubbling through sulphuric acid, can be gone through without losing more than 20 or 25 per cent of the original charge on the gas.” This means simply that the ions condense the water about them when there is an abundance of moisture in the air, but when the cloud is carried into a perfectly dry atmosphere, such as that existing in a bubble surrounded on all sides by concentrated sulphuric acid, the droplets of water evaporate and leave the charge on a molecule of air as it was at first. The 20 or 25 per cent loss of charge represents the fraction of the droplets with their charges which actually got into contact with and remained in the liquids through which the gas was being bubbled.
In order to find the charge on each ion, Townsend took the following five steps: