Sixthly, That any Iron may, in a very little time, be case hardned, as the Tradesmen call it, by casing the iron to be hardned with clay, and putting between the clay and iron a good quantity of a mixture of Urine, Soot, Sea-salt, and Horses hoofs (all which contein great quantities of Saline bodies) and then putting the case into a good strong fire, and keeping it in a considerable degree of heat for a good while, and afterwards heating, and quenching or cooling it suddenly in cold water.
Seventhly, That all kind of vitrify’d substances, by being suddenly cool’d, become very hard and brittle. And thence arises the pretty Phænomena of the Glass Drops, which I have already further explained in its own place.
Eighthly, That those metals which are not so apt to vitrifie, do not acquire any hardness by quenching in water, as Silver, Gold, &c.
These considerations premis’d, will, I suppose, make way for the more easie reception of this following Explication of the Phænomena of hardned and temper’d Steel. That Steel is a substance made out of Iron, by means of a certain proportionate Vitrification of several parts, which are so curiously and proportionately mixt with the more tough and unalter’d parts of the Iron, that when by the great heat of the fire this vitrify’d substance is melted, and consequently rarify’d, and thereby the pores of the Iron are more open, if then by means of dipping it in cold water it be suddenly cold, and the parts hardned, that is, stay’d in that same degree of Expansion they were in when hot, the parts become very hard and brittle, and that upon the same account almost as small parcels of glass quenched in water grow brittle, which we have already explicated. If after this the piece of Steel be held in some convenient heat, till by degrees certain colours appear upon the surface of the brightned metal, the very hard and brittle tone of the metal, by degrees relaxes and becomes much more tough and soft; namely, the action of the heat does by degrees loosen the parts of the Steel that were before streached or set atilt as it were, and stayed open by each other, whereby they become relaxed and set at liberty, whence some of the more brittle interjacent parts are thrust out and melted into a thin skin on the surface of the Steel, which from no colour increases to a deep Purple, and so onward by these gradations or consecutions, White, Yellow, Orange, Minium, Scarlet, Purple, Blew, Watchet, &c. and the parts within are more conveniently, and proportionately mixt; and so they gradually subside into a texture which is much better proportion’d and closer joyn’d, whence that rigidness of parts ceases, and the parts begin to acquire their former ductilness.
Now, that ’tis nothing but the vitrify’d metal that sticks upon the surface of the colour’d body, is evident from this, that if by any means it be scraped and rubb’d off, the metal underneath it is white and clear; and if it be kept longer in the fire, so as to increase to a considerable thickness, it may, by blows, be beaten off in flakes. This is further confirm’d by this observable, that that Iron or Steel will keep longer from rusting which is covered with this vitrify’d case: Thus also Lead will, by degrees, be all turn’d into a litharge; for that colour which covers the top being scum’d or shov’d aside, appears to be nothing else but a litharge or vitrify’d Lead.
This is observable also in some sort, on Brass, Copper, Silver, Gold, Tin, but is most conspicuous in Lead: all those Colours that cover the surface of the Metal being nothing else, but a very thin vitrifi’d part of the heated Metal.
The other Instance we have, is in Animal bodies, as in Pearls, Mother of Pearl-shels, Oyster-shels, and almost all other kinds of stony shels whatsoever. This have I also sometimes with pleasure observ’d even in Muscles and Tendons. Further, if you take any glutinous substance and run it exceedingly thin upon the surface of a smooth glass or a polisht metaline body, you shall find the like effects produced: and in general, wheresoever you meet with a transparent body thin enough, that is terminated by reflecting bodies of differing refractions from it, there will be a production of these pleasing and lovely colours.
Nor is it necessary, that the two terminating Bodies should be both of the same kind, as may appear by the vitrified Laminæ on Steel, Lead, and other Metals, one surface of which Laminæ is contiguous to the surface of the Metal, the other to that of the Air.
Nor is it necessary, that these colour’d Laminæ should be of an even thickness, that is, should have their edges and middles of equal thickness, as in a Looking-glass-plate, which circumstance is only requisite to make the Plate appear all of the same colour; but they may resemble a Lens, that is, have their middles thicker then their edges; or else a double concave, that is, be thinner in the middle then at the edges; in both which cases there will be various coloured rings or lines, with differing consecutions or orders of Colours; the order of the first from the middle outwards being Red, Yellow, Green, Blew, &c. And the latter quite contrary.
But further, it is altogether necessary, that the Plate, in the places where the Colours appear, should be of a determinate thickness: First, It must not be more then such a thickness, for when the Plate is increased to such a thickness, the Colours cease; and besides, I have seen in a thin piece of Muscovy-glass, where the two ends of two Plates, which appearing both single, exhibited two distinct and differing Colours; but in that place where they were united, and constituted one double Plate (as I may call it) they appeared transparent and colourless. Nor, Secondly, may the Plates be thinner then such a determinate cize; for we alwayes find, that the very outmost Rim of these flaws is terminated in a white and colourless Ring.