From whatever source we procure light, it is the same in character, differing only in intensity. In its action upon matter, we have the phenomena of transmission, of reflection, of refraction, of colour, of polarisation, and of vision, to engage our attention.
A beam of white light falls upon a plate of colourless glass, and it passes freely through it, losing but little of its intensity; the largest portion being lost by reflection from the first surface upon which the light impinges. If the glass is roughened by grinding, we lose more light by absorption and by reflection from the asperities of the roughened surface; but if we cover that face with any oleaginous fluid, as, for instance, turpentine, its transparency is restored. We have thus direct proof that transparency to light is due to molecular condition. This may be most strikingly shown by an interesting experiment of Sir David Brewster’s:—
If a glass tube is filled with nitrous acid vapour, which is of a dull red colour, it admits freely the passage of the red and orange rays with some of the others, and, if held upright in the sunshine, casts a red shadow on the ground; by gently warming it with a spirit-lamp, whilst in this position, it acquires a much deeper and blacker colour, and becomes almost impervious to any of the rays of light; but upon cooling it again recovers its transparency.
It has also been stated by the same exact experimentalist, that having brought a purple glass to a red heat, its transparency was improved, so that it transmitted green, yellow, and red rays, which it previously absorbed; but the glass recovered its absorptive powers as it cooled. A piece of yellowish-green glass lost its transparency almost entirely by being heated. Native yellow orpiment becomes blood-red upon being warmed, when nearly all but the red rays are absorbed; and pure phosphorus, which is of a pale yellow colour, and transmits freely all the coloured rays upon being melted, becomes very dark, and transmits no light.
Chemistry affords numerous examples of a very slight change of condition, producing absolute opacity in fluids which were previously diaphanous.[88]
Charcoal absorbs all the light which falls upon it, but in some of its states of combination, and in the diamond, which is pure carbon, it is highly transparent. Gold and silver beaten into thin leaves are permeated by the green and blue rays, and the metals in combination with acids are all of them more or less transparent. What becomes of the light which falls upon and is absorbed by bodies, is a question which we cannot yet, notwithstanding the extensive observations that have been made by some of the most gifted of men, answer satisfactorily. In all probability, as already stated, it is permanently retained within their substances; and many of the experiments of exciting light in bodies when in perfect darkness, by the electric spark and other means, appear to support the idea of light becoming latent or hidden.
No body is absolutely transparent; some light is lost in passing even through ethereal space, and still more in traversing our atmosphere.
Amongst the most curious instances of absorption is that which is uniformly discovered in the solar spectrum, particularly when we examine it with a telescope. We then find that the coloured rays are crossed by a great number of dark bands or lines, giving no light; these are generally called Fraunhofer’s dark lines, as it was to the indefatigable exertions of that experimentalist, and by the aid of his beautiful instruments, that most of them were discovered and measured, and enumerated, although they were previously noticed by Dr. Wollaston. It is quite clear that those lines represent rays which have been absorbed in their passage from the sun to the earth: although some of them have no doubt undergone absorption within the limits of the earth’s atmosphere, we have every reason to believe, with Sir John Herschel, that the principal absorption takes place in the atmosphere of the sun.[89]
It has been proved by Dr. Miller, that the number of those dark lines is continually varying with the alteration of atmospheric conditions;[90] and the evidences which have been afforded, of peculiar states of absorption by the gaseous envelope of the earth,—during the prosecution of investigations on the chemical agencies of the sun’s rays,—are of a sufficiently convincing character.