Discoveries and Inventions of the Nineteenth Century

by Robert Routledge

The process of electro-plating may be practised by the aid of apparatus of very simple character. Fig. [264] shows all that is necessary for obtaining perfect casts in copper of seals, small medals, &c. A A is a section of a common tumbler; B B is a tube, made by rolling some brown paper round a ruler, uniting the edge with sealing-wax, and closing the bottom by a plug of cork, round which the paper may be tied by a string, or in any other convenient manner. The tumbler contains a solution of sulphate of copper, and the tube is filled with water, to which about one-twentieth of its bulk of sulphuric acid has been added. A strip of amalgamated zinc, or a piece of thick amalgamated zinc wire, is placed in the tube, and a piece of copper bell-wire is twisted round the top of it, and has attached to its other extremity, and immersed in the copper solution, the article which is to be covered with copper. We may suppose that this is to be a cast in white wax or in plaster of one side of a medal. The cast is carefully covered with black lead by means of a soft brush, and the copper wire is inserted in such a manner as to be in contact with the black lead at some part. When the apparatus has been left for some hours in the position represented, a deposit of copper will be found over the blackleaded surface, and it will be a perfect impression of the wax cast.

Such a copper cast, or any article in copper having a perfectly clean surface, can be readily covered by a film of silver by means of a similar arrangement, where a solution of cyanide of potassium, in which some chloride of silver has been dissolved, is made to take the place of the sulphate of copper. Electro-plating with the precious metals has become a commercial industry of great importance; and this process has completely superseded the old plan of covering the metallic article to be plated with an amalgam of silver or of gold, and then exposing it to heat, which volatized the mercury, leaving a thin film of gold or of silver adhering to the baser metal. On the large scale a battery of several cells is used for electro-plating, and the articles are immersed in the metallic solutions as the negative poles of the battery; any required thickness of deposit being given according to the length of the time they remain. At the works of Messrs. Elkington, of Birmingham, these operations are conducted on a grand scale. The liquid there employed for silvering is a solution of cyanide of silver in cyanide of potassium, and the positive pole is formed of a plate of silver, which dissolves in proportion as the metal is deposited on the negative pole. As the charging of batteries is a troublesome operation, and their action is liable to variations which affect the strength of the currents, the more uniform, more convenient, and more economical mode of producing currents by magneto-electricity, which will presently be described, has been to a great extent substituted for the voltaic battery.

Fig. 265.—A Current producing a Magnet.

The wire conveying a current not only affects a magnetic needle in the manner already described, but itself possesses magnetic properties, of which, indeed, its action on the needle is the result and the indication. If such a wire be plunged into iron filings, it will be found that the filings are attracted by it: they cling in a layer of uniform thickness round its whole circumference and along its whole length, and the moment the connection with the battery is broken they drop off. This experiment shows that every part of the wire conveying a current is magnetic, and it may be proved that the action is not intercepted by the interposition of any non-magnetic material. Thus the action of the wire upon the magnetic needle takes place equally well through glass, copper, lead, or wood. Consequently, if we cover the wire with a layer of gutta-percha, or over-spin it with silk or cotton, we shall obtain like results on our filings, and if we coil the covered wire round a bar of iron, while the non-conducting covering of the wire will compel the current to circulate through all the turns of the coil, it will not interfere with the magnetic action on each particle of the bar. Whenever this is done it is found that the iron is converted into a powerful magnet so long as the current passes. Fig. [265] represents in a striking manner the result when the current is made to circulate through numerous convolutions of the wire; and as each turn adds its effect to that of the rest, magnets of enormous strength may be formed by sufficiently increasing the number of the turns. The end of the iron bar is shown projecting from the axis of the coil, and below it is placed a shallow wooden bowl, containing a number of small iron nails. The instant the battery connection is completed these nails leap up to the magnetic pole, and group themselves round it in the manner shown in the cut; and again, when the current is interrupted, the iron reverts to its ordinary condition, the magnetism vanishes, and the nails drop down in an instant. These effects may be produced again and again, as often as the current flows and is broken. A magnet so produced is called an electro-magnet, to distinguish it from the ordinary permanent steel magnets. By coiling the conducting wire round a bar of iron which has been bent into the form of a horse-shoe, very powerful magnets may be produced, and enormous weights may be supported by the force of the magnetic attraction so evoked. Fig. [266] represents the apparatus for experiments of this kind, in which weights exceeding a ton can be sustained.

Fig. 266.—An Electro-magnet.

Here, then, we have a striking instance of the subtile agent electricity, evoked by the contact of a few pieces of zinc with dilute acid, showing itself capable of exerting an enormous mechanical force. Engines have been constructed in which this force is turned to account to produce rotatory motion as a source of power. Such engines have certain advantages for special purposes; but the money cost for expenditure of material for power so obtained is, at least, sixty times greater than in the case of the steam engine. It is, however, in producing mechanical effects at a distance that the electric current finds the most interesting practical application of its magnetic properties. These are the actions which are so extensively utilized in the construction of telegraphic instruments, of clocks regulated by electric communication with a standard time-keeper, and of many ingenious self-registering instruments. The telegraph will be described in the next article, and we shall also have occasion in subsequent articles to describe some of the other applications of electro-magnetic and electro-chemical force.

INDUCED CURRENTS.

These very remarkable phenomena were discovered by the illustrious Faraday, in 1830, and this discovery, and that of magneto-electricity, may be ranked among the most memorable of his many brilliant contributions to electric science. Let two wires be stretched parallel and very near to each other, but not in contact. Let the extremities of one wire, which we shall term A, be connected with a galvanometer (page [415]), so that the existence of any current through the wire may be instantly indicated. Let the two extremities of the other wire, B, be put into connection with the poles of a battery. The moment the connection is complete, and the battery current begins to rush through B, a deflection of the galvanometer needle will be observed, indicating a current of very short duration through A in the opposite direction to the battery current through B. This induced current, which is called the secondary current, does not continue to flow through A: it occurs merely at the time the primary or battery current is established; and though the latter continues to flow through the wire, B, no further effect is produced in the other wire. When, however, the battery connection is broken, and the primary current ceases to flow, at that instant there is set up in the wire, A, another momentary secondary current, but this one is in the same direction as the battery current. This is termed the direct secondary current, in opposition to the former, which is called the inverse current.