It now remains to describe in a few words a method of photography which was, and still is, much practised, namely, the collodion process. The collodion solution is prepared by dissolving one part of pyroxylin (gun-cotton) in ninety parts of ether and sixty of alcohol. The pyroxylin for this purpose may be obtained by steeping cotton-wool for a few minutes in a mixture of nitre and sulphuric acid, with certain precautions which need not here be mentioned. To the solution of collodion is added a certain quantity of iodide of potassium, or of iodide of ammonium; and sometimes other substances also are mixed with the solution with a view of increasing the sensitiveness of the plate when ready for exposure. Some of the collodion solution is poured on a well-cleaned plate of glass, which is placed horizontally; it spreads over the plate, and the excess having been poured back into the bottle, the evaporation of the liquids leaves the glass covered with a thin uniform transparent film, which firmly adheres. The next operation is to render the plate sensitive by means of the “silver bath.” This is a neutral solution of nitrate of silver, one part to fifteen of pure water, which is placed in a trough of glass or porcelain, Fig. [311]. By the aid of a proper support the plate is introduced quickly and steadily into the solution, immediately after the collodion film has been formed on its surface. In two or three minutes the layer of collodion becomes impregnated with iodide of silver, and when taken out of the bath, the plate exhibits a creamy-looking surface. The operation of sensitizing the plate by the silver bath must be performed in a room to which no light has access, except that which has passed through red or yellow glass, or a semi-transparent yellow screen.
The plate is now ready for immediate exposure in the camera. It is placed in the dark slide, in which it is conveyed to the camera; and there the image of the object is allowed to fall upon it for a time, which varies, according to the intensity of the light and the nature of the object, from 3 seconds to 45 seconds. The slide is withdrawn from the camera, and taken again to the “dark” room, i.e., where only yellow or red light can reach it. If the plate be now examined, it will be found to present no trace of an image. A latent one, however, exists; and it is developed by pouring over the plate a solution of pyrogallic acid—one part to 480 of water, with commonly a little alcohol and acetic acid added. When it is desired to intensify the image still more, a few drops of the nitrate of silver solution is added to the developing solution immediately before pouring it on the plate. When the picture has become sufficiently distinct, it is washed with pure water, and then immersed in a strong solution of hyposulphite of soda. The last operation is termed by photographers “fixing” the picture, and the substance employed in it is invaluable to the art. It acts as a ready solvent of all the salts of silver which remain on the plate; and the discovery of this property of the hyposulphites by Sir J. Herschel, in 1839, marked an era in photography. The picture is then thoroughly washed in cold water, in order that the hyposulphite of soda may be entirely dissolved out. It is then dried, warmed before a fire, and finally the film is covered with a coat of transparent varnish, by which it is protected from mechanical injury. The image here is negative—that is, the strongest lights of the object appear as the darkest tints in the picture, and vice versâ. From it any number of positive pictures may be obtained by means of the sensitive paper prepared with chloride of silver as in Fox Talbot’s plan.
As it is a tedious, and perhaps, in some cases, an impossible operation to completely remove all traces of silver salts and hyposulphites from photographs, they have frequently been found to fade; but this is rarely the case with well-prepared specimens. Processes have, however, been devised by which absolute permanence is secured for the photograph. One of the best of these is known as the Carbon Printing Process, and, as improved by Mr. Swan, it is thus practised:
A solution of gelatine is coloured by the addition of Indian ink, or any other pigment which will give the desired tone. This solution is spread over sheets of paper which are then dried. In this condition the paper may be preserved for any length of time without any special precautions. When it is required for use, it is floated, with the gelatine-covered side downwards, in a solution of bichromate of potash, and then dried; but these operations must be carried on in the dark. The paper is exposed under a negative photograph, with which its prepared side is in contact. The effect of the light is to render insoluble the gelatine on all those parts on which it has fallen, and this action extends to a depth in the layer proportionate to the intensity of the illumination. The object is, therefore, to wash away all the soluble gelatine and the colour with which it is mixed; but this soluble gelatine is mainly on the side of the film which is in contact with the paper. The gelatine surface is therefore made to adhere to another piece of paper by means of some substance insoluble in water; and when this has been done, the whole is immersed in warm water. Then the soluble gelatine is soon dissolved; the first paper floats off, and the insoluble gelatine, holding the Indian ink or other colouring matter in its substance, remains attached by the cement. As the thickness of the layer rendered insoluble is in proportion to the intensity of the light passing through each part of the negative, the picture will be presented in all the proper gradations of light and shade.
Fig. 311.
The “wet collodion” process, that has been described on the preceding page, maintained an almost undisputed hold for more than twenty years in the practice of photography in all branches, and it was not until after the publication of the first edition of the present work that a new era in the art was commenced by the introduction of what is known as the dry plate gelatino-bromide process, to which the present enormous popularity of photography as a recreative art is due. The difficulties of manipulation, the necessity for extensive experience, and for special and cumbersome appliances were obstacles it at once removed. And not only so, but the whole scope of the art was extended; for work that was before supposed impracticable, even to the most expert professional photographer, became the amusement of the amateur. Here, we may remark in passing, that photography is greatly indebted for this, and many other improvements, to the enthusiasm of the amateur, which has accelerated the development of the art to a remarkable extent. The collodion process itself admitted of being modified as a dry plate method, by coating the film with a preservative solution of tannin, gum, albumen, or other substance, and then drying the plates, of course in a dark place. This plan made it possible to practise out-door photography with ease, and such plates were, at one time, much used for landscape photography, but they have now been almost superseded by the gelatine plates. It was Mr. Bennet, who, in 1874, first introduced the use of sensitive emulsions of gelatine, and the advantages offered by their use, caused them to be soon adopted by landscape and amateur photographers. In 1878, Mr. Bennet showed, that these plates could be made wonderfully rapid in their action, so that portraits, etc., could be taken by them in an unprecedentedly short time. The preparation of the dry gelatine plates was then commenced on a large scale, and these were found so convenient, and reliable in use, that they were adopted by the professional photographers, who had hitherto adhered to the wet collodion and silver bath, from long habit and established associations. The collodion processes are, however, still much used, and are preferred by many to the gelatine plates; indeed, it is admitted, that only by the former can certain desirable qualities of negatives be obtained, which are of great importance in some applications of the art.
There are, it need hardly be said, many modifications of the processes recommended for preparing gelatino-bromide dry plates, and each manufacturer of the various kinds offered for sale has, no doubt, his own special plan and formula. In all, a very fine and carefully selected quality of gelatine is the medium in which the sensitive salts are embedded. An “emulsion” is prepared by adding to warm gelatine solution exactly determined quantities of solutions of certain compounds, of which a bromide (usually bromide of potassium) and silver nitrate are the essential ones, together with a small proportion of iodide of potassium. Minute quantities of iodine, hydrochloric acid, etc., are also often prescribed as additions. The mixture has to be heated, at the boiling temperature, for three quarters of an hour, then cooled, and mixed with more gelatine solution, or, instead of using acid and iodine and boiling, a little ammonia is added. When cold and set, the gelatine is washed with cold water, while squeezed through canvas, or after it has been cut into thin strips. It is then drained, dissolved at a gentle heat, and filtered warm. The clean glass plates are coated over with it, at the temperature of 120° F., and are set aside in a perfectly horizontal position until the gelatine has set, when they are placed for twenty-four hours in a drying cupboard, maintained at 80° F. It will be understood that these operations are conducted in a room where no light enters, except through a frame of ruby-coloured glass, and the plates, when dry, are carefully packed and stored in light-tight boxes. They are marvellously sensitive, and receive the photographic impression in about one-sixtieth (1
60th) of the time required for wet collodion plates. Half a second exposure in the camera may be sufficient to impress the image of a well lighted landscape, even when a very small stop is used, and it is not unusual to employ for extra sensitive plates, a so-called “instantaneous shutter,” when the exposure may be no more than 1
80th to 1
100th of a second, and yet obtain a perfectly strong image. Dry plates are manufactured in vast numbers in many large establishments, and the operations are carried on to a great extent by the aid of machinery, by which the plates are uniformly coated and automatically carried into drying chambers, etc.
If photography were popular before the introduction of the dry gelatino-bromide plates, it has since become a hundred-fold more so. Indeed, the camera is now seen everywhere, and few are the family circles in which at least one amateur practitioner of the art is not to be found; indeed, the technical terms of the art have become “Familiar in their mouths as household words.” The daguerrotype, notwithstanding its cost, had no sooner become a practicable process for taking likenesses, than it began to supersede miniature painting, and how rapidly it rose into general favour may be inferred from the fact that, in 1850, ten years after its introduction, it was estimated that in the United States of America, at least ten thousand persons had made it their profession, and, probably half as many more were occupied in making and selling chemicals, plates, cameras, lenses, mounting cases, and other apparatus connected with its practice. Such being the demand for photographic portraits, at the period when the sitter had, as we have already seen, to remain motionless for two whole minutes in sunlight, we can hardly be surprised at the increased popularity the art has acquired in the last decade, when a picture can be produced with one-hundredth the length of sitting, and at about the same reduction of cost. It may here be mentioned, that Daguerre’s process is still occasionally used for special purposes; it was, for instance, the method selected for obtaining the photographic records in the expedition sent out by the French Government, in 1874, to observe the transit of Venus.
