A question has sometimes been asked as to the most important discovery in astronomy which has been made in the century that has just closed. If, by the most important discovery, we mean that which has most widely extended our knowledge of the Universe, I do not think there need be much hesitation in stating the answer. It seems to me beyond doubt that the most astonishing discovery of the last century in regard to the heavenly bodies is that which has revealed the elementary substances of which the orbs of heaven are composed. This discovery is the more interesting and instructive because it has taught us that the materials of the sun, of the stars, and of the nebulæ are essentially the elements of which our own earth is formed, and with which chemists had already become well acquainted.
We know, of course, that this earth, no matter how various may be the rocks and minerals which form its crust, and how infinite the variety of objects, organic and inorganic, which diversify its surface, is really formed from different combinations of about eighty different elements. There are gases like oxygen and hydrogen, there are other substances like carbon and sulphur, and there are metals like iron and copper. These elements are sometimes met with in their free or uncombined state, like oxygen in the atmosphere, or like gold in Klondike. More frequently they are found in combination, and in such combinations the characters of the constituent elements are sometimes completely transformed. A deadly gas and a curious metal, which burns as it floats on water, most certainly renounce their special characters when they unite to form the salt on our breakfast-table. Who would have guessed, if the chemist had not told him, that in every wheelbarrowful of ordinary earth there are pounds of silvery aluminium, and that marble is largely composed of an extremely rare metal, which but few people have ever seen?
Until the middle of the century just completed it seemed utterly impossible to form any notion as to the substances actually present in the sun. How could anyone possibly discern them by the resources of the older chemists? It might well have been doubted whether the elements of which the sun was made were the elements of which our earth was formed, and with which ordinary chemistry had made us familiar. Just as the animals and plants which met the gaze of the discoverers when they landed in the New World were essentially different from those in the Old World, so it might have been supposed, with good share of reason, that this great solar orb, ninety-three million miles distant, would be composed of elements totally different from those with which dwellers on the earth had been permitted to become acquainted.
This great discovery of the last century revealed to us the character of the elements which constitute the sun. It also added the astonishing information that they are essentially the same elements as those of which our earth itself and all which it contains are formed.
If any one had asked in the early years of the century what those elements were which entered into the composition of the sun, the question would have been deemed a silly one; it would have been regarded as hopelessly beyond the possibility of solution, and it would have been as little likely to receive an answer as the questions people sometimes ask now as to the possible inhabitants on Mars.
But about the middle of the century a new era dawned; the wonderful method of spectroscopic analysis was discovered, and it became possible to examine the chemistry of the sun. The most important result was to show that the elements which enter into the composition of the sun are the same elements which enter into the composition of the earth. The student of the solar chemistry enjoys, however, one advantage over the terrestrial chemist, if it be an advantage to have his science simplified to the utmost extent. Chemistry would, however, lose its chief interest if all the elements remained as obstinately neutral as argon, and disdained alliance with all other elements. It would seem that those elements which most eagerly enter into combination here, and which resist with such vehemence our efforts to divorce them, must renounce all chemical union when exposed to the tremendous temperature of the sun.
Those elements which unite with the utmost eagerness at ordinary temperatures, seem to become indifferent to each other when subjected to the extremes of heat and cold. Potassium unites fiercely with oxygen in the most familiar of all chemical experiments. Potassium is indeed a strange metal, for it is of such small density that a piece cast on a basin of water will float like a chip of wood. It has such avidity for oxygen that it will decompose the water to wrench the molecules of oxygen from those of hydrogen. The union of the metal with the gas generates such heat that the strange substance bursts into flame. This is what takes place at the ordinary temperatures in the well-known experiment of the chemical lecture-table. But at extreme temperatures the greed of potassium for oxygen abates, if it does not vanish altogether. In those excessively low temperatures at which Professor Dewar experiments chemical affinities languish. He has reduced oxygen to a liquid, and he tells us that “a berg of silvery potassium might float for ever untarnished on an ocean of liquid oxygen.” At the excessively high temperature of the electric arc the oxygen and the potassium, whose union has been accomplished with such vehemence, cease to possess affinity, and they separate again.
The solar chemistry seems to know no combination. If a drop of water were transferred to the sun and subjected to the heat of the solar surface, it must immediately undergo decomposition. That which was a drop of water here would not remain a drop of water there; it would be at once resolved into its component elements of oxygen and hydrogen. The considerations just given greatly simplify the search for the particular bodies which are at present in the sun. We have only to test for the presence of each of eighty elements. We have not to take account of the thousands of chemical combinations of which these elements are susceptible under terrestrial conditions.
We are specially indebted to the late Professor Henry Rowland, of Baltimore, for a profound study of the solar spectrum. In his great work he enumerates thirty-six elements present in the sun, and the number may be increased now by at least two. Eight elements he classes as doubtful, fifteen are set down as absent from the solar spectrum, and several had not been tried. Iron stands foremost among all the solar elements, so far as the number of its lines are concerned. No fewer than 2,000 lines in the spectrum of the sun are attributed to this element. At the other end of the list lead is found. There is only one line apparently due to this metal. Carbon is represented by about 200 lines, and calcium by about 75. If, however, we test the significance of lines not by their number, but by their intensity, then iron no longer heads the list, its place being taken by calcium (Fig. [42]). Among the elements which Rowland sets down as not contributing any recognisable lines to the solar spectrum we may mention arsenic and sulphur, phosphorus, mercury, and gold.
Of the more prominent solar elements there are two or three of such special importance that we pause to give them a little consideration. Who does not remember the delight of the first occasion in childhood when he was permitted to peep into a bird’s-nest and there see a group of eggs, often so exquisitely marked or so delicately tinted? How beautiful they seemed as they lay in their cosy receptacle concealed with so much cunning! Among other delightful recollections of early youth many will recall a ramble by the sea-shore. We may suppose the tide had retreated, and with other objects left by the sea on the gleaming sand a little cowrie shell is found. How enchanted we were with our prize! How we looked at the curious marks on its lips, and the inimitable beauty of its tints!