Air-dried starch contains from 15 to 20 per cent of water; but this can be completely removed, without altering the starch in any way, by heating for some time at 100° C.
The starch granules from different sources vary considerably in size and shape, and can generally be identified by observation under the microscope.
The most characteristic reaction of starch is the blue color which it gives with iodine. The reaction is most marked with starch paste or soluble starch, but even dry starch granules are colored blue when moistened with a solution of iodine in water containing potassium iodide, or with tincture of iodine.
When hydrolyzed, either by boiling with dilute acids or under the influence of enzymes, starch undergoes a series of decompositions, yielding first dextrins, then maltose, and finally glucose. These transformations can be traced by the iodine color reaction, as starch will show its characteristic blue, dextrins purple or rose-red, and maltose and glucose no color with iodine.
Dextrins may occur in plants as transition products in the transformation of starch into sugars, or vice versa. Most commonly, however, they are artificial products resulting from the partial hydrolysis of starch in the laboratory or factory. They are amorphous substances, which are readily soluble in water, forming sticky solutions which are often used as adhesives ("library paste" is a common example of a very concentrated preparation of this kind). They are precipitated from solution by alcohol, but not by lead subacetate (distinction from starch). They are strongly dextrorotatory (specific rotatory power +192° to +196°); are not fermented by yeast alone, but readily undergo hydrolysis to glucose which does ferment. There are several different modifications, or forms, of dextrins, depending upon the extent to which the simplification of the starch molecule by hydrolysis is carried. Three fairly definite forms are generally recognized, as follows: amylo-dextrin, or soluble starch, slightly soluble in cold water, readily so in hot water, giving a blue color with iodine; erythro-dextrin easily soluble in water, neutral taste, red color with iodine; and achroo-dextrin, easily soluble in water, sweetish taste, no color with iodine.
Commercial dextrin, which is much used in the preparation of mucilages and adhesive pastes, is prepared by heating dry starch to about 250° C. It is composed chiefly of achroo-dextrin, mixed with varying quantities of erythro-dextrin and glucose.
Glycogen, or "animal starch," is one of the most widely distributed reserve foods of the animal body; in fact, it is the only known form of carbohydrate-reserve in animal tissues. But it is present only rarely in plants. It occurs in certain fungi, particularly in yeasts. In the animal body, glycogen is found in all growing cells; also in the muscles and blood; but most largely in the liver, where it is stored in large quantities. The glycogen found in yeasts is identical with that found in animal tissues. The quantity of glycogen in a yeast cell increases rapidly as the yeast grows during the fermentation process.
Glycogen is a white, amorphous compound, readily soluble in hot water, forming an opalescent solution similar in appearance to the solutions of soluble starch. It is strongly dextrorotatory (specific rotatory power +190°), is colored brown by iodine, and is hydrolyzed to dextrin and maltose, and finally to glucose.
Lichenin, para dextran, and para isodextran are dextrosans which have been isolated from various lower plants. They all yield glucose when completely hydrolyzed. They resemble starch in chemical properties, but differ from it in physical form, etc.