CHAPTER X
FATS AND OILS, WAXES, AND LIPOIDS
Included in this group are several different kinds of compounds which have similar physical properties, and which, in general, belong to the type of organic compounds known as esters, i.e., alcoholic salts of organic acids. The terms "oil," "fat," and "wax," are generally applied more or less indiscriminately to any substance which has a greasy feeling to the touch and which does not mix with, but floats on, water. There are many oils which are of mineral origin which are entirely different in composition from natural fats. These have no relation to plant life and will not be considered here.
The natural fats, vegetable oils, and plant waxes are all esters. There is no essential difference between a fat and an oil, the latter term being usually applied to a fat which is liquid at ordinary temperatures. The waxes, however, are different in chemical composition from the fats and oils, being esters of monohydric alcohols of high molecular weight, such as cetyl alcohol, C16H33OH, myristic alcohol, C30H61OH, and cholesterol, C27H45OH; whereas the fats and oils are all esters of the trihydric alcohol glycerol, C3H5(OH)3. Lipoids are much more complex esters, having some nitrogenous, or phosphorus-containing, group and sometimes a sugar in combination with the fatty acids and glycerol which make up the characteristic part of their structure.
In general, waxes and lipoids have a harder consistency than fats: but this is not always the case, since "wool-fat" and spermaceti, both of which are true waxes in composition, are so nearly liquid in form as to be commonly called fats; while certain true fats, like "Japan wax," are so hard as to be commonly designated as waxes. It is plain that physical properties alone cannot be relied upon in the classification of these bodies. In fact, there is no single definite property by which members of this group can be accurately identified. There are many other types of substances belonging to entirely different chemical groups, which have oily, or fat-like, properties.
A. FATS AND OILS
OCCURRENCE
Fats and oils are widely distributed in plants. They occur very commonly in the reproductive organs, both spores and seeds, as reserve food material. In fungi, oils are often found in the spores, but sometimes also in sclerotia, mycelia, or filaments. For example, the sclerotia of ergot have been found to contain as much as 60 per cent of oil. In higher plants, many seeds contain high percentages of oil, so as to make them commercial sources for edible or lubricating oils, such as olive oil, rape-seed oil, cottonseed oil, castor oil, corn oil, sunflower-seed oil, etc., etc. Nuts often contain large proportions of oil, the kernel of the Brazil nut, for example, sometimes contains as high as 70 per cent of oil, while an oil content of 50 per cent, or more, is common in almonds, walnuts, etc.
Oils also occur as reserve food material in other storage organs of plants, such as the tubers of certain flowering plants, and the roots of many species of orchids. Sometimes the appearance of oils in the stems of trees, or the winter leaves of evergreens, seems to be only temporary and to occur only during periods of very low temperatures.
Much less frequently, fats or oils are found in the vegetative organs of plants, as in the leaves of evergreens. Their appearance and functions in these organs seem to be much less certain than in the other cases cited above; although in rare cases a considerable proportion of oily material has been found to exist in definite association with the chloroplasts.