Cave Deposits
Beautiful mineral deposits occur in some natural caves. Deposits that look like icicles, called stalactites, are found hanging from the ceiling of a cave. Other deposits, stalagmites, are like the stalactites except that they jut upward from the floor. Columns are formed from stalactites and stalagmites that have joined together. In addition, some caves contain sheet-like deposits that are spread along the ceiling, floor, and walls. These deposits are called flowstone. [Calcite] is one of the minerals that commonly form cave deposits.
Just a few of the caves in Texas contain these deposits. They occur mostly in the [limestone] rocks that are south and southwest of the [Llano uplift] area of central Texas. Some of the commercial caves that contain good examples of [calcite] deposits are located near Boerne in Kendall County and near Sonora in Sutton County. Calcite deposits also occur in Longhorn Cavern, a large cave located in the Longhorn Cavern State Park of Burnet County. These caves were formed by underground waters that moved through cracks and pores in the limestone rocks and dissolved passageways in them. After the cave passages were made, water containing dissolved calcium carbonate dripped into the cave. As it evaporated, this water left behind a deposit of calcium carbonate—the mineral calcite.
You can better understand how the cave deposits are formed by watching icicles grow in wet, freezing weather. First, small hanging drops of water freeze, and a small icicle forms. Then, as more water drips over it and freezes, the icicle grows longer and wider. Some of the water drips completely over the icicle and falls to the ground. There, it either freezes into a sheet of ice, or it begins to build upward to form an upside-down icicle. The water dripping down in the caves evaporates instead of freezing, and in doing so it leaves behind a deposit of [calcite].
[Calcite] stalactites and stalagmites in the Caverns of Sonora, Sutton County, Texas. Photograph courtesy of the Travel and Information Division of the Texas Highway Department.
Concretions
[Limestone], [shale], and other [sedimentary] rocks commonly have scattered throughout them masses of other rocks and minerals, such as [limonite], [chert], and [pyrite]. These masses are called concretions. Concretions may be round or oval, or they may have odd, irregular shapes. They—such as some of the limonite concretions of east Texas—even may look like gourds or sweet potatoes. Concretions generally are harder than the surrounding rocks. Some are smaller than peas, but others are several feet wide. (The word [nodule] is used to describe small, rounded concretions as well as other small, rounded mineral occurrences.)
It is believed that some concretions form at the same time as the rocks in which they occur. Other concretions develop after the rocks themselves have formed. These are deposited by underground water that contains dissolved mineral matter. The water seeps through the rocks and deposits mineral matter around an object in the rock, such as a fossil or a grain of [sand], to form a concretion.